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1,2:5,6-Di-O-cyclohexylidene-D-mannitol_Molecular_structure_CAS_76779-67-4)
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1,2:5,6-Di-O-cyclohexylidene-D-mannitol

Catalog No. 36655 Name Sigma Aldrich
CAS Number 76779-67-4 Website http://www.sigmaaldrich.com
M. F. C18H30O6 Telephone 1-800-521-8956
M. W. 342.4272 Fax
Purity ≥98.0% (CH) Email
Storage Chembase ID: 151178

SYNONYMS

Title
1,2:5,6-二-O-亚环己基-D-甘露醇
IUPAC name
(1S,2S)-1,2-bis[(2R)-1,4-dioxaspiro[4.5]decan-2-yl]ethane-1,2-diol
IUPAC Traditional name
(1S,2S)-1,2-bis[(2R)-1,4-dioxaspiro[4.5]decan-2-yl]ethane-1,2-diol

DATABASE IDS

MDL Number MFCD09863049
PubChem SID 24862667
Beilstein Number 4235336
CAS Number 76779-67-4

PROPERTIES

Empirical Formula (Hill Notation) C18H30O6
Grade purum
Purity ≥98.0% (CH)
Melting Point 103-104 °C
Melting Point 103-105 °C(lit.)
Optical Rotation [α]20/D +6.0±0.5°, c = 3% in methylene chloride
MSDS Link Download
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
German water hazard class 3

DETAILS

Description (English)
Other Notes
Starting material for preparing the unstable 2,3-O-cyclohexylidene-D-glyceraldehyde 1; this aldehyde was employed in highly diastereoselective addition reactions 2,3
Description (简体中文)
Other Notes
制备不稳定 2,3-O-环亚己基-D-甘油醛的原料1;这种醛可用于高非对映选择性加成反应2,3

REFERENCES