9-Borabicyclo[3.3.1]nonyl trifluoromethanesulfonate solution

• Catalog No.: 15575
• CAS Number: 62731-43-5
• M. F.: C9H14BF3O3S
• M. W.: 270.0768696

SYNONYMS

• Title: 9-硼杂双环[3.3.1]壬基三氟甲磺酸酯 溶液
• IUPAC name: (1s,5s)-9-borabicyclo[3.3.1]nonan-9-yl trifluoromethanesulfonate
• IUPAC Traditional name: (1s,5s)-9-borabicyclo[3.3.1]nonan-9-yl trifluoromethanesulfonate
• Synonyms: 9-BBN triflate solution; 9-BBN·CF3SO3; 9-[[(Trifluoromethyl)sulfonyl]oxy]-9-borabicyclo[3.3.1]nonane; 9-BBN 三氟甲磺酸酯 溶液

DATABASE IDS

• MDL Number: MFCD00167981
• Beilstein Number: 995656
• CAS Number: 62731-43-5
• PubChem SID: 24849562

PROPERTIES

• Concentration: ~0.5 M in hexane
• Empirical Formula (Hill Notation): C9H14BF3O3S
• Grade: purum
• Flash Point: -22 °C
• Flash Point: -8 °F
• European Hazard Symbols: Flammable (F)
• European Hazard Symbols: Corrosive (C)
• European Hazard Symbols: Nature polluting (N)
• RID/ADR: UN 2924 3/PG 2
• Risk Statements: 11-34-48/20-51/53-62-65-67
• Safety Statements: 16-26-36/37/39-45-61-62
• Hazard Class: 3
• UN Number: 2924
• Packing Group: 2
• German water hazard class: 3

DETAILS

Description (English)

Other Notes
Reagent used for the formation of enol borinates from carbonyl compounds employed in stereoselective aldol reactions7,8,9
Application
Reactant for:
• Preparation of a dialkylborenium ion stabilized by an N-heterocyclic carbene1
• Mukaiyama aldol addition2
• Preparation of porphyrin dimethyldioxanyl tolyl derivative complex3
• Preparation of palladium porphyrin complexes4
• Boron-mediated β-alkoxy Me ketone aldol addition reactions5
• Enolization agent6

Description (简体中文)

Other Notes
用于由羰基化合物形成烯醇硼酸酯（用于不对称羟醛反应）的试剂7,8,9
Application
Reactant for:
• Preparation of a dialkylborenium ion stabilized by an N-heterocyclic carbene1
• Mukaiyama aldol addition2
• Preparation of porphyrin dimethyldioxanyl tolyl derivative complex3
• Preparation of palladium porphyrin complexes4
• Boron-mediated β-alkoxy Me ketone aldol addition reactions5
• Enolization agent6