N,N-Diisopropylcarbamoyl chloride

• Catalog No.: 38360
• CAS Number: 19009-39-3
• M. F.: C7H14ClNO
• M. W.: 163.64516
• Purity: ≥98.0% (AT)

SYNONYMS

• Title: 二异丙基甲胺酰氯
• IUPAC name: N,N-bis(propan-2-yl)carbamoyl chloride
• IUPAC Traditional name: N,N-diisopropylcarbamoyl chloride

DATABASE IDS

• CAS Number: 19009-39-3
• Beilstein Number: 1754834
• MDL Number: MFCD00015013
• EC Number: 242-743-5

PROPERTIES

• Grade: purum
• Linear Formula: [(CH3)2CH]2NCOCl
• Purity: ≥98.0% (AT)
• Boiling Point: 90-93 °C/15 mmHg(lit.)
• Melting Point: 57-59 °C(lit.)
• Melting Point: 57-59 °C
• European Hazard Symbols: Corrosive (C)
• RID/ADR: UN 3261 8/PG 2
• Risk Statements: 34
• Safety Statements: 26-36/37/39-45
• Hazard Class: 8
• UN Number: 3261
• Packing Group: 2
• German water hazard class: 3

DETAILS

Description (English)

Other Notes
Carbamates of allylic alcohols can be lithiated and reacted with carbonyl compounds to give γ-hydroxy carbonyl compounds (homoaldol reaction) 1; Chiral allylic carbamates are enantioselectively deprotonated with retention 2

Description (简体中文)

Other Notes
烯丙醇的氨基甲酸酯可锂化并与羰基化合物反应生成 γ-羟基羰基化合物（同型羟醛反应）1；对手性烯丙基氨基甲酸酯有保留地进行对映选择性去质子化2