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2-Cyanoethyl N,N,N′,N′-tetraisopropylphosphordiamidite_Molecular_structure_CAS_102691-36-1)
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2-Cyanoethyl N,N,N′,N′-tetraisopropylphosphordiamidite

Catalog No. 28314 Name Sigma Aldrich
CAS Number 102691-36-1 Website http://www.sigmaaldrich.com
M. F. C15H32N3OP Telephone 1-800-521-8956
M. W. 301.407841 Fax
Purity ≥98.0% (31P-NMR) Email
Storage Chembase ID: 89774

SYNONYMS

Title
2-氰乙基N,N,N′,N′-四异丙基亚磷酰二胺
IUPAC name
3-({bis[bis(propan-2-yl)amino]phosphanyl}oxy)propanenitrile
IUPAC Traditional name
3-{[bis(diisopropylamino)phosphanyl]oxy}propanenitrile
Synonyms
双(二异丙基氨基)(2-氰乙氧基)膦
Bis(diisopropylamino)(2-cyanoethoxy)phosphine

DATABASE IDS

MDL Number MFCD00012213
Beilstein Number 3590103
CAS Number 102691-36-1

PROPERTIES

Grade purum
Linear Formula {[(CH3)2CH]2N}2POCH2CH2CN
Purity ≥98.0% (31P-NMR)
Boiling Point 100 °C/0.5 mmHg(lit.)
Density 0.949 g/mL at 25 °C(lit.)
Flash Point 60 °C
Flash Point 140 °F
Refractive Index n20/D 1.470(lit.)
Refractive Index n20/D 1.470
GHS Pictograms GHS02
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H261-H315-H319-H335
European Hazard Symbols Explosive Explosive (E)
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P231 + P232-P261-P305 + P351 + P338-P422
RID/ADR UN 1993 3/PG 3
Risk Statements 5-6-36/37/38
Safety Statements 3-26-36
Storage Temperature 2-8°C
Hazard Class 3
UN Number 1993
Packing Group 3
German water hazard class 3

DETAILS

Description (English)
Other Notes
Phosphitylation reagent used in nucleotide synthesis by the phosphite method 1,2; Phosphitylation of other compounds3
Description (简体中文)
Other Notes
用于通过亚磷酸盐法合成核苷酸的亚磷酰化试剂1,2;其他化合物的亚磷酰化3

REFERENCES