(R)-(+)-N-Benzyl-α-methylbenzylamine

• Catalog No.: 13765
• CAS Number: 38235-77-7
• M. F.: C15H17N
• M. W.: 211.30218
• Purity: ≥98.5% (sum of enantiomers, GC)

SYNONYMS

• Title: (R)-(+)-N-苄基-α-甲基苄胺
• IUPAC name: benzyl[(1R)-1-phenylethyl]amine
• IUPAC Traditional name: benzyl[(1R)-1-phenylethyl]amine
• Synonyms: (R)-(+)-N-Benzyl-1-phenylethylamine; (R)-(+)-N-苄基-1-苯乙胺; (R)-(+)-N-(1-苯乙基)苄胺; (R)-(+)-N-(1-Phenylethyl)benzylamine

DATABASE IDS

• MDL Number: MFCD00015010
• CAS Number: 38235-77-7
• Beilstein Number: 3589990
• PubChem SID: 24848339

PROPERTIES

• Grade: puriss.
• Linear Formula: C6H5CH(CH3)NHCH2C6H5
• Purity: ≥98.5% (sum of enantiomers, GC)
• Boiling Point: 171 °C/15 mmHg(lit.)
• Density: 1.01 g/mL at 25 °C(lit.)
• Flash Point: 113 °C
• Flash Point: 235.4 °F
• Optical Rotation: [α]20/D +58±2°, c = 5% in ethanol
• Refractive Index: n20/D 1.564(lit.)
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 36/37/38
• Safety Statements: 26-36
• German water hazard class: 3

DETAILS

Description (English)

Other Notes
The metal amide of this base is used for diastereoselective Michael additions yielding β-amino acids1; Base for enantioselective ketone enolate formation2,3

Description (简体中文)

Other Notes
此碱的金属酰胺可用于非对映选择性 Michael 加成，生成 β-氨基酸1；以及用作合成对映选择性酮烯醇化物的碱2,3