Dichloro(3-methyl-2-butenylidene)bis(tricyclohexylphosphine)ruthenium(II)

• Catalog No.: 578681
• CAS Number: 194659-03-5
• M. F.: C41H74Cl2P2Ru
• M. W.: 800.949782

SYNONYMS

• Title: 二氯化(3-甲基-2-丁烯亚基)二(三环己基膦)钌
• IUPAC name: dichloro(3-methylbut-2-en-1-ylidene)ruthenium; bis(tricyclohexylphosphane)
• IUPAC Traditional name: dichloro(3-methylbut-2-en-1-ylidene)ruthenium; bis(tricyclohexylphosphine)
• Synonyms: Grubbs Catalyst 801; Bis(tricyclohexylphosphine)isopentenylidene ruthenium dichloride

DATABASE IDS

• PubChem SID: 24880943
• CAS Number: 194659-03-5
• MDL Number: MFCD04039970

PROPERTIES

• Empirical Formula (Hill Notation): C41H74Cl2P2Ru
• Melting Point: 160-165 °C(lit.)
• GHS Signal Word: Warning
• GHS Hazard statements: H228
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• GHS Precautionary statements: P210
• Storage Temperature: 2-8°C
• German water hazard class: 3

DETAILS

Description (English)

Other Notes
NO BULK ORDERS
Packaging
1, 5 g in glass bottle
Legal Information
US Patent No. 5,969,170 (and associated foreign equivalents of the foregoing) apply. Sale of this product conveys to the buyer a limited-use research license. For full details of this license please see sigma-aldrich.com/materialicense. For questions, please contact us at aldrich@sial.com or Materia at info@materia-inc.com.
Application
Metathesis: Ruthenium-Based Metathesis CatalystsCatalyst for:
• Olefin metathesis (Schiff base catalyst)1
• polymerization reactions2
• Cross metathesis reactions3
• Ring-closing metathesis4
• Dehydration reactions5
• Solventless ring-opening metathesis polymerization of norbornene derivatives to form polymeric thin films6
• Used for preparation of second generation Grubbs catalysts7
Kinetic application profile similar to that of Grubbs 1st Generation Catalyst.

Description (简体中文)

Other Notes
不接受大宗订购
包装
1, 5 g in glass bottle
Legal Information
美国专利5,969,170（以及上述专利的相关国外等同专利）均适用。销售该产品可向购买者转让限制使用研究许可。有关该许可的完整详细内容，请访问 sigma-aldrich.com/materialicense。如有疑问，请发送邮件至 aldrich@sial.com 与我们联系，或发送至 info@materia-inc.com 联系 Materia。
Application
Metathesis: Ruthenium-Based Metathesis CatalystsCatalyst for:
• Olefin metathesis (Schiff base catalyst)1
• polymerization reactions2
• Cross metathesis reactions3
• Ring-closing metathesis4
• Dehydration reactions5
• Solventless ring-opening metathesis polymerization of norbornene derivatives to form polymeric thin films6
• Used for preparation of second generation Grubbs catalysts7
Kinetic application profile similar to that of Grubbs 1st Generation Catalyst.