Ethyl (3-chlorobenzoyl)acetate

• Catalog No.: 559288
• CAS Number: 33167-21-4
• M. F.: C11H11ClO3
• M. W.: 226.65624
• Purity: ≥97%

SYNONYMS

• Title: (3-氯苯甲酰)乙酸乙酯
• IUPAC name: ethyl 3-(3-chlorophenyl)-3-oxopropanoate
• IUPAC Traditional name: ethyl 3-(3-chlorophenyl)-3-oxopropanoate
• Synonyms: 3-Chloro-β-oxobenzenepropanoic acid ethyl ester; Ethyl 3-(3-chlorophenyl)-3-oxopropanoate

DATABASE IDS

• CAS Number: 33167-21-4
• MDL Number: MFCD03424810
• PubChem SID: 24879812

PROPERTIES

• Linear Formula: ClC6H4COCH2CO2C2H5
• Purity: ≥97%
• Boiling Point: 257-258 °C(lit.)
• Density: 1.213 g/mL at 25 °C(lit.)
• Refractive Index: n20/D 1.5460(lit.)
• Personal Protective Equipment: Eyeshields, Gloves
• German water hazard class: 3

DETAILS

Description (English)

Packaging
1, 5 g in glass bottle
Application
Reagent / reactant involved in:
• Oxidative cross-coupling via dioxygen activation with indoles1
• Chlorination and hydrosilylation for synthesis of α-hydroxy β-amino acid derivatives2
• Precursor for substrates for chiral Lewis base-catalyzed stereoselective reduction with trichlorosilane and water3
• Intramolecular cyclization for synthesis of dihydrofurans4
• Rate acceleration of Michael reactions5
• Cerium ammonium nitrate-mediated oxidative coupling6

Description (简体中文)

包装
1, 5 g in glass bottle
Application
Reagent / reactant involved in:
• Oxidative cross-coupling via dioxygen activation with indoles1
• Chlorination and hydrosilylation for synthesis of α-hydroxy β-amino acid derivatives2
• Precursor for substrates for chiral Lewis base-catalyzed stereoselective reduction with trichlorosilane and water3
• Intramolecular cyclization for synthesis of dihydrofurans4
• Rate acceleration of Michael reactions5
• Cerium ammonium nitrate-mediated oxidative coupling6