Tricyclohexylphosphine solution

• Catalog No.: 455164
• CAS Number: 2622-14-2
• M. F.: C18H33P
• M. W.: 280.428381

SYNONYMS

• Title: 三环己基磷 溶液
• IUPAC name: tricyclohexylphosphane
• IUPAC Traditional name: tricyclohexylphosphine
• Synonyms: NSC 158657; PCy3

DATABASE IDS

• CAS Number: 2622-14-2
• MDL Number: MFCD00003853
• Beilstein Number: 957171
• PubChem SID: 24869033

PROPERTIES

• Concentration: 20 wt. % in toluene
• Linear Formula: (C6H11)3P
• Flash Point: 11 °C
• Flash Point: 51.8 °F
• GHS Signal Word: Danger
• GHS Hazard statements: H225-H304-H315-H319-H335 + H336-H361d-H373
• European Hazard Symbols: Flammable (F)
• European Hazard Symbols: Harmful (Xn)
• Personal Protective Equipment: Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P210-P261-P281-P301 + P310-P305 + P351 + P338-P331
• RID/ADR: UN 1294 3/PG 2
• Risk Statements: 63-11-36/37/38-48/20-65-67
• Safety Statements: 16-26-36/37-62
• Hazard Class: 3
• UN Number: 1294
• Packing Group: 2
• German water hazard class: 3

DETAILS

Description (English)

Application
Reagent used as a ligand for a range of metal-catalyzed organic transformations.
Catalyst for:
• Carbonylative Suzuki-coupling of benzyl halides with potassium aryltrifluoroborates1
• Suzuki-Miyaura reactions of aryl sulfonates / halides with arylboronic acids2
• Synthesis of an acromelic acid A analog based 11C-labeled PET tracer3
• Synthesis of (-)-Exiguolide and its analogues4
• Allylation of zinc enolates5
Packaging
100, 500 g in glass bottle

Description (简体中文)

Application
Reagent used as a ligand for a range of metal-catalyzed organic transformations.
Catalyst for:
• Carbonylative Suzuki-coupling of benzyl halides with potassium aryltrifluoroborates1
• Suzuki-Miyaura reactions of aryl sulfonates / halides with arylboronic acids2
• Synthesis of an acromelic acid A analog based 11C-labeled PET tracer3
• Synthesis of (-)-Exiguolide and its analogues4
• Allylation of zinc enolates5
包装
100, 500 g in glass bottle