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Di-μ-chlorobis[5-chloro-2-[(4-chlorophenyl)(hydroxyimino-κN)methyl]phenyl-κC]palladium dimer_Molecular_structure_CAS_287410-78-0)
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Di-μ-chlorobis[5-chloro-2-[(4-chlorophenyl)(hydroxyimino-κN)methyl]phenyl-κC]palladium dimer

Catalog No. 668923 Name Sigma Aldrich
CAS Number 287410-78-0 Website http://www.sigmaaldrich.com
M. F. C26H16Cl6N2O2Pd2 Telephone 1-800-521-8956
M. W. 813.97544 Fax
Purity 97% Email
Storage Chembase ID: 152882

SYNONYMS

Title
二-μ-氯双[5-氯-2-[(4-氯苯基)(羟基亚氨基-κN)甲基]苯基-κC]钯二聚物
IUPAC name
bis(chloro({5-chloro-2-[(4-chlorophenyl)(hydroxyimino)methyl]phenyl})palladium)
IUPAC Traditional name
bis(chloro({5-chloro-2-[(4-chlorophenyl)(hydroxyimino)methyl]phenyl})palladium)
Synonyms
Di-chlorobis[5-chloro-2-[(4-chlorophenyl)(hydroxyimino)methyl]phenyl-C]di-palladium
Nájera Catalyst I
Nájera 催化剂 I
二-氯双[5-氯-2-[(4-氯苯基)(羟基亚氨基)甲基]苯基-C]二钯

DATABASE IDS

PubChem SID 24885009
CAS Number 287410-78-0

PROPERTIES

GHS Hazard statements H302-H312-H332
European Hazard Symbols Harmful Harmful (Xn)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P280
Risk Statements 20/21/22
Safety Statements 36/37
German water hazard class 3
GHS Pictograms GHS07
GHS Signal Word Warning
Empirical Formula (Hill Notation) C26H16Cl6N2O2Pd2
Purity 97%

DETAILS

Description (English)
Packaging
1 g in glass bottle
250 mg in glass bottle
Application
Catalyst for:
• Suzuki coupling1
• Suzuki-Miyaura coupling2
• Najera palladacycle-catalyzed intermolecular Heck reaction of Morita-Baylis-Hillman adducts3
• Hiyama cross-coupling4
• Palladium-catalyzed acylation of terminal alkynes with acid chlorides5
• Copper and amine free Sonogashira coupling reaction6
Highly effective catalyst for multiple aryl vinylation via Heck coupling. Palladacycle catalyst employed in a variety of carbon-carbon bond forming reactions.
Description (简体中文)
包装
1 g in glass bottle
250 mg in glass bottle
Application
Catalyst for:
• Suzuki coupling1
• Suzuki-Miyaura coupling2
• Najera palladacycle-catalyzed intermolecular Heck reaction of Morita-Baylis-Hillman adducts3
• Hiyama cross-coupling4
• Palladium-catalyzed acylation of terminal alkynes with acid chlorides5
• Copper and amine free Sonogashira coupling reaction6
用于通过 Heck 偶联实现多芳基乙烯化的高效催化剂。用于多种碳-碳键形成反应的环钯催化剂。

REFERENCES