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(-)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene_Molecular_structure_CAS_147253-67-6)
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(-)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene

Catalog No. 14788 Name Sigma Aldrich
CAS Number 147253-67-6 Website http://www.sigmaaldrich.com
M. F. C18H28P2 Telephone 1-800-521-8956
M. W. 306.362442 Fax
Purity ≥95.0% Email
Storage Chembase ID: 141283

SYNONYMS

Title
(-)-1,2-双[(2R,5R)-2,5-二甲基磷]苯
IUPAC name
(2R,5R)-1-{2-[(2R,5R)-2,5-dimethylphospholan-1-yl]phenyl}-2,5-dimethylphospholane
IUPAC Traditional name
(2R,5R)-1-{2-[(2R,5R)-2,5-dimethylphospholan-1-yl]phenyl}-2,5-dimethylphospholane
Synonyms
(R,R)-Methyl-DUPHOS
(2R,2’R,5R,5′R)-2,2′,5,5′-Tetramethyl-1,1′-(o-phenylene)diphospholane
(R,R)-甲基-DUPHOS
(2R,2'R,5R,5′R)-2,2′,5,5′-四甲基-1,1′-(邻亚苯基)二磷烷
(R,R)-Me-DUPHOS

DATABASE IDS

CAS Number 147253-67-6
PubChem SID 24848835
MDL Number MFCD00142336
Beilstein Number 4810602

PROPERTIES

Empirical Formula (Hill Notation) C18H28P2
Purity ≥95.0%
Melting Point 66-76 °C
Optical Rotation [α]20/D -420±15°, c = 0.5 in methylene chloride
MSDS Link Download
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
German water hazard class 3

DETAILS

Description (简体中文)
包装
250 mg in glass bottle
Application
DuPhos and BPE Ligands: Highly Efficient Privileged Ligands
Description (English)
Packaging
250 mg in glass bottle
Application
DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

REFERENCES