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1,1,1,3,3,3-Hexakis(dimethylamino)diphosphazenium tetrafluoroborate_Molecular_structure_CAS_137334-98-6)
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1,1,1,3,3,3-Hexakis(dimethylamino)diphosphazenium tetrafluoroborate

Catalog No. 52586 Name Sigma Aldrich
CAS Number 137334-98-6 Website http://www.sigmaaldrich.com
M. F. C12H36BF4N7P2 Telephone 1-800-521-8956
M. W. 427.2132748 Fax
Purity ≥98.0% (T) Email
Storage Chembase ID: 148661

SYNONYMS

Title
1,1,1,3,3,3-六(二甲氨基)二磷腈四氟硼酸盐
IUPAC name
3,3,5,5-tetrakis(dimethylamino)-2,6-dimethyl-2,4,6-triaza-3λ5,5λ5-diphosphahepta-3,4-dien-4-ium; tetrafluoroboranuide
IUPAC Traditional name
3,3,5,5-tetrakis(dimethylamino)-2,6-dimethyl-2,4,6-triaza-3λ5,5λ5-diphosphahepta-3,4-dien-4-ium tetrafluoroborate
Synonyms
Phosphazenium tetrafluoroborate P2-BF4
Bis[tris(dimethylamino)phosphoranylidene]ammonium tetrafluoroborate
双[三(二甲氨基)正膦亚基]四氟硼酸铵
磷腈四氟硼酸盐 P2-BF4

DATABASE IDS

MDL Number MFCD00216714
Beilstein Number 5470923
CAS Number 137334-98-6
PubChem SID 24874514

PROPERTIES

Linear Formula [[(CH3)2N]3P=]2N(BF4)
Purity ≥98.0% (T)
Melting Point ≥260 °C(lit.)
GHS Pictograms GHS05
GHS Signal Word Danger
GHS Hazard statements H314
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
GHS Precautionary statements P280-P305 + P351 + P338-P310
RID/ADR UN 3261 8/PG 2
Risk Statements 14-34
Safety Statements 26-27-36/37/39-45
Supplemental Hazard Statements Reacts violently with water.
Hazard Class 8
UN Number 3261
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Other Notes
Phase transfer catalyst directing enolate alkylation towards O-substitution1; Starting material for preparing the corresponding fluoride, an extremely reactive naked fluoride, with KF2
Packaging
5 g in poly bottle
Application
Phosphazene Bases: a Family of Extremely Strong, Non-Ionic, Non-Charged Nitrogen-Bases
Description (简体中文)
Other Notes
将烯醇化物烷化反应导向 O-取代的相转移催化剂1;用于与 KF 反应制备相应氟化物(强反应性无保护氟化物)的原料2
包装
5 g in poly bottle
Application
Phosphazene Bases: a Family of Extremely Strong, Non-Ionic, Non-Charged Nitrogen-Bases

REFERENCES