Trimethyl(trifluoromethyl)silane solution

• Catalog No.: 91862
• CAS Number: 81290-20-2
• M. F.: C4H9F3Si
• M. W.: 142.1949696

SYNONYMS

• Title: 三氟甲基三甲基硅烷 溶液
• IUPAC name: trimethyl(trifluoromethyl)silane
• IUPAC Traditional name: trifluoromethyltrimethylsilane
• Synonyms: Ruppert′s reagent; TFMTMS; Ruppert-Prakash reagent; Trifluoromethyltrimethylsilane; (Trifluoromethyl)trimethylsilane

DATABASE IDS

• MDL Number: MFCD00145454
• CAS Number: 81290-20-2
• Beilstein Number: 4241868
• PubChem SID: 24889567

PROPERTIES

• Concentration: ~2.0 M in THF
• Linear Formula: (CH3)3SiCF3
• Density: 0.91 g/mL at 20 °C
• Flash Point: -17 °C
• Flash Point: 1.4 °F
• Refractive Index: n20/D 1.386
• GHS Signal Word: Danger
• GHS Hazard statements: H225-H319-H335
• European Hazard Symbols: Flammable (F)
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P210-P261-P305 + P351 + P338
• RID/ADR: UN 1993 3/PG 2
• Risk Statements: 11-19-36/37
• Safety Statements: 16-26
• Supplemental Hazard Statements: May form explosive peroxides.
• Hazard Class: 3
• UN Number: 1993
• Packing Group: 2
• German water hazard class: 3

DETAILS

Description (English)

Packaging
10, 50 mL in glass bottle
Application
Reactant for:
• Silver-mediated C-H trifluoromethylation of arenes1
• Preparation of trifluoromethyl ketone analog of L-arginine having contrasting inhibitory activity against human arginase I and histone deacetylase 82
• Organocatalyzed regio- and enantioselective allylic trifluoromethylation of Morita-Baylis-Hillman adducts3
• Palladium-catalyzed oxidative trifluoromethylation of indoles4
• Preparation of 5-HT1A antagonists5
• Used as difluorocarbene source6

Description (简体中文)

包装
10, 50 mL in glass bottle
Application
Reactant for:
• Silver-mediated C-H trifluoromethylation of arenes1
• Preparation of trifluoromethyl ketone analog of L-arginine having contrasting inhibitory activity against human arginase I and histone deacetylase 82
• Organocatalyzed regio- and enantioselective allylic trifluoromethylation of Morita-Baylis-Hillman adducts3
• Palladium-catalyzed oxidative trifluoromethylation of indoles4
• Preparation of 5-HT1A antagonists5
• Used as difluorocarbene source6