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1-(Trimethylsilyl)imidazole

Catalog No. 92751 Name Sigma Aldrich
CAS Number 18156-74-6 Website http://www.sigmaaldrich.com
M. F. C6H12N2Si Telephone 1-800-521-8956
M. W. 140.25838 Fax
Purity ≥98.0% (T) Email
Storage Chembase ID: 8470

SYNONYMS

Title
1-(三甲基硅基)咪唑
IUPAC name
1-(trimethylsilyl)-1H-imidazole
IUPAC Traditional name
1-(trimethylsilyl)imidazole
Synonyms
TMSI
N-三甲基硅基咪唑
N-Trimethylsilylimidazole
TSIM

DATABASE IDS

MDL Number MFCD00005280
CAS Number 18156-74-6
PubChem SID 24889712
EC Number 242-040-3
Beilstein Number 606148

PROPERTIES

Empirical Formula (Hill Notation) C6H12N2Si
Grade synthesis grade
Purity ≥98.0% (T)
Purity ≥98.0%
Boiling Point 93-94 °C/14 mmHg(lit.)
Density 0.957 g/mL at 20 °C
Density 0.956 g/mL at 25 °C(lit.)
Flash Point 6 °C
Flash Point 42.8 °F
Refractive Index n20/D 1.475(lit.)
GHS Pictograms GHS02
GHS Pictograms GHS07
GHS Signal Word Danger
GHS Hazard statements H225-H315-H319-H335
European Hazard Symbols Flammable Flammable (F)
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P210-P261-P305 + P351 + P338
RID/ADR UN 1993 3/PG 2
Risk Statements 11-36/37/38
RTECS NI8700000
Safety Statements 16-26-33
Storage Temperature 2-8°C
Hazard Class 3
UN Number 1993
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Other Notes
Powerful silylating agent, particularly for alcohols1,2,3; Synthesis of acyl imidazolides4
Description (简体中文)
Other Notes
高效硅烷化试剂,特别适合用于醇1,2,3、酰基咪唑类的合成4

REFERENCES