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tert-Butyl hydroperoxide solution_Molecular_structure_CAS_75-91-2)
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tert-Butyl hydroperoxide solution

Catalog No. 19999 Name Sigma Aldrich
CAS Number 75-91-2 Website http://www.sigmaaldrich.com
M. F. C4H10O2 Telephone 1-800-521-8956
M. W. 90.121 Fax
Purity Email
Storage Chembase ID: 105404

SYNONYMS

Title
叔丁基过氧化氢 溶液
IUPAC name
2-methylpropane-2-peroxol
IUPAC Traditional name
tert-butyl hydroperoxide
Synonyms
2-Hydroperoxy-2-methylpropane
TBHP
1,1-Dimethylethyl hydroperoxide

DATABASE IDS

Beilstein Number 1098280
CAS Number 75-91-2
PubChem SID 24851951
MDL Number MFCD00002130

PROPERTIES

Safety Statements 3/7-14-26-36/37/39-45-61-62
Storage Temperature 2-8°C
Hazard Class 5.2
UN Number 3105
German water hazard class 3
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Pictograms GHS06
GHS Pictograms GHS08
GHS Pictograms GHS09
GHS Signal Word Danger
GHS Hazard statements H226-H302-H304-H311 + H331-H314-H317-H336-H341-H411
European Hazard Symbols Oxidising Oxidising (O)
European Hazard Symbols Toxic Toxic (T)
European Hazard Symbols Nature polluting Nature polluting (N)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P261-P273-P280-P301 + P310-P305 + P351 + P338-P310
RID/ADR UN 3105 5.2
Risk Statements 7-10-21/22-23-34-43-51/53-65-68
Concentration ~5.5 M in nonane (over molecular sieve 4 Å)
Linear Formula (CH3)3COOH
Quality packed in FEP bottles
Density 0.82 g/mL at 20 °C
Flash Point 29 °C
Flash Point 84.2 °F
Refractive Index n20/D 1.400

DETAILS

Description (English)
Other Notes
Safe and stable oxidant for the Sharpless epoxidation1,2Reactant also used as a redox initiator3 and oxidant4
Packaging
25, 100 mL in PFA/FEP bottle
Description (简体中文)
Other Notes
Safe and stable oxidant for the Sharpless epoxidation1,2Reactant also used as a redox initiator3 and oxidant4
包装
25, 100 mL in PFA/FEP btl

REFERENCES