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Oxalyl chloride_Molecular_structure_CAS_79-37-8)
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Oxalyl chloride

Catalog No. 75760 Name Sigma Aldrich
CAS Number 79-37-8 Website http://www.sigmaaldrich.com
M. F. C2Cl2O2 Telephone 1-800-521-8956
M. W. 126.9262 Fax
Purity ≥96.0% (AT) Email
Storage Chembase ID: 78496

SYNONYMS

Title
草酰氯
IUPAC name
oxalic dichloride
IUPAC Traditional name
oxalyl chloride
Synonyms
Ethanedioyl dichloride
乙二酰二氯

DATABASE IDS

PubChem SID 24886877
MDL Number MFCD00000704
Beilstein Number 1361988
CAS Number 79-37-8
EC Number 201-200-2

PROPERTIES

MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US)
GHS Precautionary statements P261-P280-P305 + P351 + P338-P310
RID/ADR UN 2922 8/PG 1
Risk Statements 14-23-29-34
Safety Statements 26-36/37/39-45
Supplemental Hazard Statements Contact with water liberates toxic gas., Reacts violently with water.
Hazard Class 8
UN Number 2922
Packing Group 1
German water hazard class 2
GHS Pictograms GHS05
GHS Pictograms GHS06
GHS Signal Word Danger
GHS Hazard statements H314-H331
European Hazard Symbols Toxic Toxic (T)
Linear Formula ClCOCOCl
Purity ≥96.0% (AT)
Quality dist.
Boiling Point 62-65 °C(lit.)
Density 1.5 g/mL at 20 °C(lit.)
Melting Point -10--8 °C(lit.)
Refractive Index n20/D 1.429(lit.)
Vapor Density 4.4 (vs air)
Vapor Pressure 150 mmHg ( 20 °C)

DETAILS

Description (English)
Packaging
2.5 kg in glass bottle
25, 100, 500 mL in glass bottle
Application
Reactant involved in:
• Synthesis of N-heterocyclic ynones and ynediones, used to activate carboxylic acids1
• Chlorination and halogenation2
• Three-component [3+2] cycloadditions3
• Reactions with organostannanes4
• Synthesis of cyclopentenones5
• Carbonylations, used as a carbonyl synthon6
Description (简体中文)
包装
2.5 kg in glass bottle
25, 100, 500 mL in glass bottle
Application
Reactant involved in:
• Synthesis of N-heterocyclic ynones and ynediones, used to activate carboxylic acids1
• Chlorination and halogenation2
• Three-component [3+2] cycloadditions3
• Reactions with organostannanes4
• Synthesis of cyclopentenones5
• Carbonylations, used as a carbonyl synthon6

REFERENCES