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(R)-(+)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline_Molecular_structure_CAS_164858-78-0)
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(R)-(+)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline

Catalog No. 72575 Name Sigma Aldrich
CAS Number 164858-78-0 Website http://www.sigmaaldrich.com
M. F. C24H24NOP Telephone 1-800-521-8956
M. W. 373.427221 Fax
Purity ≥97.0% (CHN) Email
Storage Chembase ID: 88671

SYNONYMS

Title
(R)-(+)-2-[2-(二苯基膦)苯基]-4-异丙基-2-噁唑啉
IUPAC name
(4R)-2-[2-(diphenylphosphanyl)phenyl]-4-(propan-2-yl)-4,5-dihydro-1,3-oxazole
IUPAC Traditional name
(4R)-2-[2-(diphenylphosphanyl)phenyl]-4-isopropyl-4,5-dihydro-1,3-oxazole
Synonyms
(R)-(+)-2-[2-(二苯基膦)苯基]-4,5-二氢-4-异丙基-噁唑
(R)-(+)-2-[2-(Diphenylphosphino)phenyl]-4,5-dihydro-4-isopropyl-oxazole

DATABASE IDS

PubChem SID 24886425
Beilstein Number 8156604
MDL Number MFCD02684553
CAS Number 164858-78-0

PROPERTIES

Empirical Formula (Hill Notation) C24H24NOP
Purity ≥97.0% (CHN)
Melting Point 85-90 °C
Optical Rotation [α]20/D +48±3°, c = 1.4% in chloroform
MSDS Link Download
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
German water hazard class 3

DETAILS

Description (English)
Other Notes
Asymmetric alkylation with an iridium catalyst1; Chiral ligand for asymmetric reduction reaction2
Packaging
100, 500 mg in glass bottle
Description (简体中文)
Other Notes
可与铱催化剂发生不对称烷基化反应1;不对称还原反应的手性配体2
包装
100, 500 mg in glass bottle

REFERENCES