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(R)-(+)-N,N-Bis(2-diphenylphosphinoethyl)-1-phenylethylamine_Molecular_structure_CAS_161583-25-1)
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(R)-(+)-N,N-Bis(2-diphenylphosphinoethyl)-1-phenylethylamine

Catalog No. 14826 Name Sigma Aldrich
CAS Number 161583-25-1 Website http://www.sigmaaldrich.com
M. F. C36H37NP2 Telephone 1-800-521-8956
M. W. 545.633202 Fax
Purity ≥98.0% (CHN) Email
Storage Chembase ID: 152547

SYNONYMS

Title
(R)-(+)-N,N-双(2-二苯基膦乙基)-1-苯乙胺
IUPAC name
bis[2-(diphenylphosphanyl)ethyl][(1R)-1-phenylethyl]amine
IUPAC Traditional name
bis[2-(diphenylphosphanyl)ethyl][(1R)-1-phenylethyl]amine
Synonyms
(R)-(+)-N,N-双(2-二苯基膦乙基)-α-甲基苄胺
(R)-(+)-N,N-Bis(2-diphenylphosphinoethyl)-α-methylbenzylamine

DATABASE IDS

CAS Number 161583-25-1
MDL Number MFCD00233839
PubChem SID 24848897

PROPERTIES

Empirical Formula (Hill Notation) C36H37NP2
Purity ≥98.0% (CHN)
Optical Rotation [α]20/D +4.5±0.7°, c = 1% in acetone
GHS Pictograms GHS05
GHS Signal Word Danger
GHS Hazard statements H314
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
GHS Precautionary statements P280-P305 + P351 + P338-P310
RID/ADR UN 3259 8/PG 3
Risk Statements 34
Safety Statements 26-36/37/39-45
Hazard Class 8
UN Number 3259
Packing Group 3
German water hazard class 3

DETAILS

Description (English)
Other Notes
Diphosphine ligand for iridium-cat. reduction of unsaturated ketones to allylalcohols1
Packaging
500 mg in glass bottle
Description (简体中文)
Other Notes
双膦配体,用于铱催化的不饱和酮还原反应生成烯丙醇1
包装
500 mg in glass bottle

REFERENCES