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Phosphazene base P1-t-Bu-tris(tetramethylene)_Molecular_structure_CAS_161118-67-8)
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Phosphazene base P1-t-Bu-tris(tetramethylene)

Catalog No. 79432 Name Sigma Aldrich
CAS Number 161118-67-8 Website http://www.sigmaaldrich.com
M. F. C16H33N4P Telephone 1-800-521-8956
M. W. 312.433781 Fax
Purity ≥97.0% (NT) Email
Storage Chembase ID: 152536

SYNONYMS

Title
磷腈配体 P1-叔丁基三(四亚甲基)
IUPAC name
tert-butyl[tris(pyrrolidin-1-yl)-λ5-phosphanylidene]amine
IUPAC Traditional name
tert-butyl[tris(pyrrolidin-1-yl)-λ5-phosphanylidene]amine
Synonyms
BTPP
叔丁基亚氨基-三(吡咯烷)膦
tert-Butylimino-tri(pyrrolidino)phosphorane

DATABASE IDS

PubChem SID 24887459
Beilstein Number 9100965
MDL Number MFCD00214188
CAS Number 161118-67-8

PROPERTIES

Hazard Class 8
UN Number 3267
Packing Group 2
German water hazard class 3
GHS Pictograms GHS05
GHS Signal Word Danger
GHS Hazard statements H314
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P280-P305 + P351 + P338-P310
RID/ADR UN 3267 8/PG 2
Risk Statements 34
Safety Statements 26-36/37/39-45
Storage Temperature 2-8°C
Empirical Formula (Hill Notation) C16H33N4P
Purity ≥97.0% (NT)
Boiling Point 119-122 °C/0.1 mmHg(lit.)
Density 1.022 g/mL at 20 °C(lit.)
Melting Point -24 °C(lit.)
Refractive Index n20/D 1.509

DETAILS

Description (English)
Other Notes
This phosphazene base is 1.4 pK units more basic than the hexamethyl analogue (Fluka 79408)1,2; Compare also with the analogue BEMP (Fluka 20025)
Packaging
5, 25 mL in glass bottle
Application
Phosphazene Bases: a Family of Extremely Strong, Non-Ionic, Non-Charged Nitrogen-Bases
Description (简体中文)
Other Notes
这种磷腈配体的碱性比六甲基类似物 (Fluka 79408) 大 1.4 个 pK 单位1,2;与类似物 BEMP (Fluka 20025) 相比亦然
包装
5, 25 mL in glass bottle
Application
Phosphazene Bases: a Family of Extremely Strong, Non-Ionic, Non-Charged Nitrogen-Bases

REFERENCES