(1S,9S)-1,9-Bis[(tert-butyldimethylsiloxy)methyl]-5-cyanosemicorrin

• Catalog No.: 14556
• CAS Number: 105251-52-3
• M. F.: C24H45N3O2Si2
• M. W.: 463.804
• Purity: ≥97.0%

SYNONYMS

• Title: (1S,9S)-1,9-双[(叔丁基二甲基甲硅烷氧基)甲基]-5-氰基半咕啉
• IUPAC name: 2-[(2S)-2-{[(tert-butyldimethylsilyl)oxy]methyl}-3,4-dihydro-2H-pyrrol-5-yl]-2-[(5S)-5-{[(tert-butyldimethylsilyl)oxy]methyl}pyrrolidin-2-ylidene]acetonitrile
• IUPAC Traditional name: 2-[(5S)-5-{[(tert-butyldimethylsilyl)oxy]methyl}-4,5-dihydro-3H-pyrrol-2-yl]-2-[(5S)-5-{[(tert-butyldimethylsilyl)oxy]methyl}pyrrolidin-2-ylidene]acetonitrile
• Synonyms: 半咕啉手性配体 2; Semicorrin chiral ligand 2

DATABASE IDS

• CAS Number: 105251-52-3
• PubChem SID: 24848735
• MDL Number: MFCD00142698
• Beilstein Number: 5153664

PROPERTIES

• Empirical Formula (Hill Notation): C24H45N3O2Si2
• Purity: ≥97.0%
• Melting Point: 74-77 °C
• Optical Rotation: [α]20/D -63±2°, c = 1% in chloroform
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 36/37/38
• Safety Statements: 26-36
• Storage Temperature: 2-8°C
• German water hazard class: 3

DETAILS

Description (English)

Other Notes
The Cu(II) and Co(II) complexes are catalysts for enantioselective cyclopropanation and reduction reactions1,2
Packaging
10 mg in glass bottle

Description (简体中文)

Other Notes
Cu(II) 和 Co(II) 配合物为不对称环丙烷化和还原反应的催化剂1,2
包装
10 mg in glass bottle