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Borane dimethyl sulfide complex_Molecular_structure_CAS_13292-87-0)
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Borane dimethyl sulfide complex

Catalog No. 15587 Name Sigma Aldrich
CAS Number 13292-87-0 Website http://www.sigmaaldrich.com
M. F. C2H9BS Telephone 1-800-521-8956
M. W. 75.96886 Fax
Purity Email
Storage Chembase ID: 139969

SYNONYMS

Title
硼烷二甲基硫醚络合物
IUPAC name
(methylsulfanyl)methane borane
IUPAC Traditional name
dimethyl sulfide borane
Synonyms
BMS
硼烷二甲硫醚
Trihydro[thiobis[methane]]boron
Borane methyl sulfide complex
Dimethyl sulfide borane
硼烷甲基硫醚络合物

DATABASE IDS

PubChem SID 24849576
Beilstein Number 3663489
MDL Number MFCD00013189
CAS Number 13292-87-0

PROPERTIES

Concentration >90% in dimethyl sulfide
Grade technical
Linear Formula (CH3)2S · BH3
Density 0.801 g/mL at 20 °C(lit.)
Flash Point 18 °C
Flash Point 64.4 °F
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Pictograms GHS07
GHS Signal Word Danger
GHS Hazard statements H225-H260-H315-H318-H335
European Hazard Symbols Flammable Flammable (F)
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P210-P223-P231 + P232-P261-P370 + P378-P422
RID/ADR UN 3399 4.3/PG 1
Risk Statements 11-14/15-37/38-41
Safety Statements 16-26-39-43
Storage Temperature 2-8°C
Supplemental Hazard Statements Reacts violently with water.
Hazard Class 4.3
UN Number 3399
Packing Group 1
German water hazard class 3

DETAILS

Description (English)
Other Notes
Convenient and stable source of borane for hydroborations, reviews 6,7,8; Selective reduction of α-hydroxyesters9
Packaging
25, 100 mL in Sure/Seal™
Application
Reactant used as a regioselective reducing agent1,2Reactant involved in:
• Hydroboration / oxidation3,4
• Synthesis of cage compounds5
Description (简体中文)
Other Notes
方便而稳定的硼烷来源,用于硼氢化反应,综述6,7,8;α-羟基酯的选择性还原反应9
包装
25, 100 mL in Sure/Seal™
Application
Reactant used as a regioselective reducing agent1,2Reactant involved in:
• Hydroboration / oxidation3,4
• Synthesis of cage compounds5

REFERENCES