Borane dimethyl sulfide complex

• Catalog No.: 15587
• CAS Number: 13292-87-0
• M. F.: C2H9BS
• M. W.: 75.96886

SYNONYMS

• Title: 硼烷二甲基硫醚络合物
• IUPAC name: (methylsulfanyl)methane borane
• IUPAC Traditional name: dimethyl sulfide borane
• Synonyms: BMS; 硼烷二甲硫醚; Trihydro[thiobis[methane]]boron; Borane methyl sulfide complex; Dimethyl sulfide borane; 硼烷甲基硫醚络合物

DATABASE IDS

• PubChem SID: 24849576
• Beilstein Number: 3663489
• MDL Number: MFCD00013189
• CAS Number: 13292-87-0

PROPERTIES

• Concentration: >90% in dimethyl sulfide
• Grade: technical
• Linear Formula: (CH3)2S · BH3
• Density: 0.801 g/mL at 20 °C(lit.)
• Flash Point: 18 °C
• Flash Point: 64.4 °F
• GHS Signal Word: Danger
• GHS Hazard statements: H225-H260-H315-H318-H335
• European Hazard Symbols: Flammable (F)
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P210-P223-P231 + P232-P261-P370 + P378-P422
• RID/ADR: UN 3399 4.3/PG 1
• Risk Statements: 11-14/15-37/38-41
• Safety Statements: 16-26-39-43
• Storage Temperature: 2-8°C
• Supplemental Hazard Statements: Reacts violently with water.
• Hazard Class: 4.3
• UN Number: 3399
• Packing Group: 1
• German water hazard class: 3

DETAILS

Description (English)

Other Notes
Convenient and stable source of borane for hydroborations, reviews 6,7,8; Selective reduction of α-hydroxyesters9
Packaging
25, 100 mL in Sure/Seal™
Application
Reactant used as a regioselective reducing agent1,2Reactant involved in:
• Hydroboration / oxidation3,4
• Synthesis of cage compounds5

Description (简体中文)

Other Notes
方便而稳定的硼烷来源，用于硼氢化反应，综述6,7,8；α-羟基酯的选择性还原反应9
包装
25, 100 mL in Sure/Seal™
Application
Reactant used as a regioselective reducing agent1,2Reactant involved in:
• Hydroboration / oxidation3,4
• Synthesis of cage compounds5