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Diphenyliodonium chloride_Molecular_structure_CAS_1483-72-3)
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Diphenyliodonium chloride

Catalog No. 43088 Name Sigma Aldrich
CAS Number 1483-72-3 Website http://www.sigmaaldrich.com
M. F. C12H10ClI Telephone 1-800-521-8956
M. W. 316.56527 Fax
Purity ≥98.0% (AT) Email
Storage Chembase ID: 103221

SYNONYMS

Title
二苯基碘酰氯
IUPAC name
diphenyliodanium chloride
IUPAC Traditional name
diphenyliodanium chloride
Synonyms
DPI
NSC 134275

DATABASE IDS

CAS Number 1483-72-3
MDL Number MFCD00011909
PubChem SID 24866949
Beilstein Number 3574977
EC Number 216-049-8

PROPERTIES

Linear Formula (C6H5)2I+Cl-
Purity ≥98.0% (AT)
Melting Point 233-235 °C (subl.)(lit.)
GHS Pictograms GHS06
GHS Signal Word Danger
GHS Hazard statements H301-H315-H319-H335
European Hazard Symbols Toxic Toxic (T)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
GHS Precautionary statements P261-P301 + P310-P305 + P351 + P338
RID/ADR UN 2811 6.1/PG 3
Risk Statements 25-36/37/38
RTECS NN6651666
Safety Statements 26-36
Hazard Class 6.1
UN Number 2811
Packing Group 3
German water hazard class 3

DETAILS

Description (English)
Other Notes
Reagent used for electrophilic phenylation, e.g. of malonates and dithiocarboxylates8,9,10
Packaging
5, 25 g in glass bottle
Application
Reactant for:
• Copper-catalyzed cross coupling reactions of purines and diaryliodonium salts1
• Synthesis of acetylenic arylselenides2
• Sonogashira coupling reactions for the preparation of aryl alkynes3
• C-H functionalization for synthesis of (arylmethylene)oxindoles4
• Arylation of anilines5
• Studies on the visible-light photosensitive system-dlourescein yellow-bis(di-Ph iodonium)6
• Investigating the properties of direct and sensitized photolysis of dispersed photoacid generators7
Description (简体中文)
Other Notes
用于亲电苯基化反应(如丙二酸酯和二硫代羧酸酯的反应)的试剂8,9,10
包装
5, 25 g in glass bottle
Application
Reactant for:
• Copper-catalyzed cross coupling reactions of purines and diaryliodonium salts1
• Synthesis of acetylenic arylselenides2
• Sonogashira coupling reactions for the preparation of aryl alkynes3
• C-H functionalization for synthesis of (arylmethylene)oxindoles4
• Arylation of anilines5
• Studies on the visible-light photosensitive system-dlourescein yellow-bis(di-Ph iodonium)6
• Investigating the properties of direct and sensitized photolysis of dispersed photoacid generators7

REFERENCES