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Lithium borohydride

Catalog No. 62460 Name Sigma Aldrich
CAS Number 16949-15-8 Website http://www.sigmaaldrich.com
M. F. BLi Telephone 1-800-521-8956
M. W. 17.752 Fax
Purity ≥95.0% Email
Storage Chembase ID: 104255

SYNONYMS

Title
硼氢化锂
IUPAC name
lithium(1+) ion boranuide
IUPAC Traditional name
lithium(1+) ion boranuide

DATABASE IDS

EC Number 241-021-7
CAS Number 16949-15-8
MDL Number MFCD00011088
PubChem SID 24882219

PROPERTIES

Linear Formula LiBH4
Purity ≥95.0%
Density 0.666 g/mL at 25 °C(lit.)
Melting Point 275 °C (dec.)
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Pictograms GHS06
GHS Signal Word Danger
GHS Hazard statements H260-H301-H311-H314-H331
European Hazard Symbols Flammable Flammable (F)
European Hazard Symbols Toxic Toxic (T)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
GHS Precautionary statements P223-P231 + P232-P261-P280-P370 + P378-P422
RID/ADR UN 1413 4.3/PG 1
Risk Statements 14/15-23/24/25-34
RTECS ED2725000
Safety Statements 26-36/37/39-43-45
Supplemental Hazard Statements Reacts violently with water.
Hazard Class 4.3
UN Number 1413
Packing Group 1
German water hazard class 2

DETAILS

Description (English)
Other Notes
Review1; Smooth reduction of esters2,3; Reduction of acids and other functional groups with LiBH4/Me3SiCl4
Packaging
5 g in glass bottle
Description (简体中文)
Other Notes
综述1;酯的平稳还原反应2,3;用 LiBH4/Me3SiCl4 还原酸及其他官能团
包装
5 g in glass bottle

REFERENCES