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Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate_Molecular_structure_CAS_35138-22-8)
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Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Catalog No. 14694 Name Sigma Aldrich
CAS Number 35138-22-8 Website http://www.sigmaaldrich.com
M. F. C16H24BF4Rh Telephone 1-800-521-8956
M. W. 406.0718728 Fax
Purity Email
Storage Chembase ID: 94689

SYNONYMS

Title
双(1,5-环辛二烯)四氟硼酸铑(I)
IUPAC name
λ1-rhodium(1+) ion bis(cycloocta-1,5-diene) tetrafluoroboranuide
IUPAC Traditional name
λ1-rhodium(1+) ion bis(1,5-cyclooctadiene) tetrafluoroborate
Synonyms
四氟硼酸铑(I) 1,5-环辛二烯络合物
Rhodium(I) tetrafluoroborate 1,5-Cyclooctadiene complex

DATABASE IDS

MDL Number MFCD00075045
CAS Number 35138-22-8
PubChem SID 24848802

PROPERTIES

Compostion carbon content, 45.7-49.0%
Empirical Formula (Hill Notation) C16H24BF4Rh
Melting Point ~190 °C (dec.)
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Signal Word Danger
GHS Hazard statements H228-H314
European Hazard Symbols Flammable Flammable (F)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
GHS Precautionary statements P210-P280-P305 + P351 + P338-P310
RID/ADR UN 2921 8/PG 2
Risk Statements 11-34
Safety Statements 26-36/37/39-45
Hazard Class 8
UN Number 2921
Packing Group 2
German water hazard class 2

DETAILS

Description (English)
Other Notes
Rhodium complex employed for preparing cationic COD-Rh complexes with phosphine ligands, e.g. for enantioselective hydrogenation1,2,3; Hydrosilylation4
Packaging
100 mg in glass bottle
Description (简体中文)
Other Notes
用于使用膦配体制备阳离子 COD-Rh 络合物(例如不对称加氢)的铑配合物1,2,3;氢化硅烷化反应4
包装
100 mg in glass bottle

REFERENCES