Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

• Catalog No.: 14694
• CAS Number: 35138-22-8
• M. F.: C16H24BF4Rh
• M. W.: 406.0718728

SYNONYMS

• Title: 双(1,5-环辛二烯)四氟硼酸铑(I)
• IUPAC name: λ^1-rhodium(1+) ion bis(cycloocta-1,5-diene) tetrafluoroboranuide
• IUPAC Traditional name: λ^1-rhodium(1+) ion bis(1,5-cyclooctadiene) tetrafluoroborate
• Synonyms: 四氟硼酸铑(I) 1,5-环辛二烯络合物; Rhodium(I) tetrafluoroborate 1,5-Cyclooctadiene complex

DATABASE IDS

• MDL Number: MFCD00075045
• CAS Number: 35138-22-8
• PubChem SID: 24848802

PROPERTIES

• Compostion: carbon content, 45.7-49.0%
• Empirical Formula (Hill Notation): C16H24BF4Rh
• Melting Point: ~190 °C (dec.)
• GHS Signal Word: Danger
• GHS Hazard statements: H228-H314
• European Hazard Symbols: Flammable (F)
• Personal Protective Equipment: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• GHS Precautionary statements: P210-P280-P305 + P351 + P338-P310
• RID/ADR: UN 2921 8/PG 2
• Risk Statements: 11-34
• Safety Statements: 26-36/37/39-45
• Hazard Class: 8
• UN Number: 2921
• Packing Group: 2
• German water hazard class: 2

DETAILS

Description (English)

Other Notes
Rhodium complex employed for preparing cationic COD-Rh complexes with phosphine ligands, e.g. for enantioselective hydrogenation1,2,3; Hydrosilylation4
Packaging
100 mg in glass bottle

Description (简体中文)

Other Notes
用于使用膦配体制备阳离子 COD-Rh 络合物（例如不对称加氢）的铑配合物1,2,3；氢化硅烷化反应4
包装
100 mg in glass bottle