Other Notes Horner-Wittig reagent giving preferentially (E)-α,β-unsat. esters which are mildly saponified with acid6,7,8. Synthesis of derivatives by reductive alkylation9 Packaging 25, 100 mL in glass bottle Application Reactant for: • Preparation of phosphonate terminated PPH dendrimers as anti-HIV-1 agents1 • Preparation of monodehydro diketopiperazines from ketoacyl amino acid amides via acid-catalyzed cyclization2 • Preparation of α,β-unsaturated esters for use in the guanidine-catalyzed oxa-Michael addition3 • Preparation of myxopyronin B and desmethyl myxopyronin B analogs, with antibacterial activity and inhibitory activity against bacterial RNA polymerase4 • Allylation and subsequent ring-closing metathesis in presence of Grubbs′ catalyst or intramolecular rhodium-catalyzed cyclopropanation reactions5 |
Other Notes Horner-Wittig 试剂,优先生成 (E)-α,β-不饱和酯,这种酯可与酸发生轻度皂化反应6,7,8。也可用于通过还原烷基化反应合成衍生物9 包装 25, 100 mL in glass bottle Application Reactant for: • Preparation of phosphonate terminated PPH dendrimers as anti-HIV-1 agents1 • Preparation of monodehydro diketopiperazines from ketoacyl amino acid amides via acid-catalyzed cyclization2 • Preparation of α,β-unsaturated esters for use in the guanidine-catalyzed oxa-Michael addition3 • Preparation of myxopyronin B and desmethyl myxopyronin B analogs, with antibacterial activity and inhibitory activity against bacterial RNA polymerase4 • Allylation and subsequent ring-closing metathesis in presence of Grubbs′ catalyst or intramolecular rhodium-catalyzed cyclopropanation reactions5 |