L-tert-Leucinol hydrochloride

• Catalog No.: 61930
• M. F.: C6H16ClNO
• M. W.: 153.65034
• Purity: ≥99.0% (CHN)

SYNONYMS

• Title: L-叔亮氨醇 盐酸盐
• IUPAC name: (2S)-2-amino-3,3-dimethylbutan-1-ol hydrochloride
• IUPAC Traditional name: (2S)-2-amino-3,3-dimethylbutan-1-ol hydrochloride
• Synonyms: (S)-2-氨基-3,3-二甲基-1-丁醇 盐酸盐; (S)-2-Amino-3,3-dimethyl-1-butanol hydrochloride

DATABASE IDS

• PubChem SID: 24882185
• MDL Number: MFCD00077809

PROPERTIES

• Empirical Formula (Hill Notation): C6H15NO · HCl
• Purity: ≥99.0% (CHN)
• Melting Point: 196-198 °C
• Optical Rotation: [α]20/D +35±1°, c = 1% in H2O
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• German water hazard class: 3

DETAILS

Description (English)

Other Notes
Chiral auxiliary and building block which usually induces higher stereoselectivities than the corresponding derivatives of valinol; e.g. Claisen rearrangement of N-allyl ketene-N,O-acetals1; preparation of an effective C2-symmetrical catalyst for hydrosilylation of ketones2; alkylation of bicyclic N,O-acetals with keto acids3; Ullmann coupling4
Packaging
1 g in glass bottle

Description (简体中文)

Other Notes
手性助剂和结构单元，通常可比对应的缬氨醇诱导产生更高的立体选择性；如 N-烯丙基乙烯酮-N,O-缩醛1的 Claisen 重排反应；制备用于酮的氢化硅烷化的有效 C2-对称催化剂2；与酮酸进行双环 N,O-缩醛的烷基化3；Ullmann 偶联反应4
包装
1 g in glass bottle