(Ethoxycarbonylmethyl)triphenylphosphonium chloride

• Catalog No.: 02615
• CAS Number: 17577-28-5
• M. F.: C22H22ClO2P
• M. W.: 384.835641
• Purity: ≥90% (AT)

SYNONYMS

• Title: (乙氧基羰基甲基)三苯基氯化膦
• IUPAC name: (2-ethoxy-2-oxoethyl)triphenylphosphanium chloride
• IUPAC Traditional name: (2-ethoxy-2-oxoethyl)triphenylphosphanium chloride
• Synonyms: (2-Ethoxy-2-oxoethyl)triphenylphosphonium chloride

DATABASE IDS

• MDL Number: MFCD00011746
• PubChem SID: 24845340
• Beilstein Number: 3924139
• EC Number: 241-548-2
• CAS Number: 17577-28-5

PROPERTIES

• Melting Point: 120-123 °C(lit.)
• Melting Point: 120-123 °C (dec.)
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 36/37/38
• Safety Statements: 26-36
• Storage Temperature: 2-8°C
• German water hazard class: 3
• Grade: technical
• Linear Formula: CH3CH2OCOCH2P(Cl)(C6H5)3
• Purity: ≥90% (AT)

DETAILS

Description (English)

Other Notes
Starting material for preparing the Wittig-reagent6,7,8
Application
Reactant for:
• Preparation of disubstituted tetrahydrofurans as selective serotonin re-uptake inhibitors for the treatment of depression1
• Ring-opening reactions with Wittig reagents2
• Enantioselective total synthesis of the phytotoxic lactone herbarumin III via Keck′s asymmetric allylation and Sharpless epoxidation3
• Synthesis of fluorobenzofurans via microwave-assisted tandem intramolecular Wittig and Claisen rearrangement reactions4
• Preparation of phosphonium derivatives of coumarin5

Description (简体中文)

Other Notes
制备 Wittig 试剂的原料6,7,8
Application
Reactant for:
• Preparation of disubstituted tetrahydrofurans as selective serotonin re-uptake inhibitors for the treatment of depression1
• Ring-opening reactions with Wittig reagents2
• Enantioselective total synthesis of the phytotoxic lactone herbarumin III via Keck′s asymmetric allylation and Sharpless epoxidation3
• Synthesis of fluorobenzofurans via microwave-assisted tandem intramolecular Wittig and Claisen rearrangement reactions4
• Preparation of phosphonium derivatives of coumarin5