Allylboronic acid pinacol ester

• Catalog No.: 324647
• CAS Number: 72824-04-5
• M. F.: C9H17BO2
• M. W.: 168.04108
• Purity: 97%

SYNONYMS

• Title: 烯丙基硼酸频哪醇酯
• IUPAC name: 4,4,5,5-tetramethyl-2-(prop-2-en-1-yl)-1,3,2-dioxaborolane
• IUPAC Traditional name: 4,4,5,5-tetramethyl-2-(prop-2-en-1-yl)-1,3,2-dioxaborolane
• Synonyms: Pinacol allylboronate; Pinacolyl 2-propenylboronate; 4,4,5,5-tetramethyl-2-(2-propenyl)-1,3,2-dioxaborolane; 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane; 4,4,5,5-tetramethyl-2-(2-propen-1-yl)-1,3,2-dioxaborolane; Allyl pinacol boronate; 2-烯丙基-4,4,5,5-四甲基-1,3,2-二氧环戊硼烷; 丙烯基硼酸频哪醇酯

DATABASE IDS

• PubChem SID: 24859457
• MDL Number: MFCD00013347
• CAS Number: 72824-04-5

PROPERTIES

• Linear Formula: ((CH3)4C2O2)BCH2CH=CH2
• Purity: 97%
• Boiling Point: 50-53 °C/5 mmHg(lit.)
• Density: 0.896 g/mL at 25 °C(lit.)
• Flash Point: 46 °C
• Flash Point: 114.8 °F
• Refractive Index: n20/D 1.4268(lit.)
• GHS Signal Word: Warning
• GHS Hazard statements: H226-H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P261-P305 + P351 + P338
• RID/ADR: UN 1993 3/PG 3
• Risk Statements: 10-36/37/38
• Safety Statements: 26-36
• Storage Temperature: 2-8°C
• Hazard Class: 3
• UN Number: 1993
• Packing Group: 3
• German water hazard class: 3

DETAILS

Description (English)

Packaging
1, 10 g in glass bottle
Application
Reagent used for
• Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions and olefin metathesis1
• Intermolecular radical additions2
• Allylboration of aldehydes catalyzed by chiral spirobiindane diol (SPINOL) based phosphoric acids3
• Cobalt-catalyzed regioselective hydrovinylation of dienes with alkenes4
• Nucleic acid-templated energy transfer leading to a photorelease reaction5
• Stereoselective indium-catalyzed Hosomi-Sakurai reactions6 Reagent used in Preparation of
• Cyclic sulfone hydroxyethylamines as BACE1 inhibitors for reduction of Amyloid β-Peptides7
• Transmetalation of carbene Ru iodide with Ag carboxylates to give C-H-activated Ru carbene complexes as catalysts for Z-selective olefin metathesis8

Description (简体中文)

包装
1, 10 g in glass bottle
Application
Reagent used for
• Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions and olefin metathesis1
• Intermolecular radical additions2
• Allylboration of aldehydes catalyzed by chiral spirobiindane diol (SPINOL) based phosphoric acids3
• Cobalt-catalyzed regioselective hydrovinylation of dienes with alkenes4
• Nucleic acid-templated energy transfer leading to a photorelease reaction5
• Stereoselective indium-catalyzed Hosomi-Sakurai reactions6 Reagent used in Preparation of
• Cyclic sulfone hydroxyethylamines as BACE1 inhibitors for reduction of Amyloid β-Peptides7
• Transmetalation of carbene Ru iodide with Ag carboxylates to give C-H-activated Ru carbene complexes as catalysts for Z-selective olefin metathesis8