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1,1′-Bis(phenylphosphinidene)ferrocene_Molecular_structure_CAS_72954-06-4)
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1,1′-Bis(phenylphosphinidene)ferrocene

Catalog No. 567159 Name Sigma Aldrich
CAS Number 72954-06-4 Website http://www.sigmaaldrich.com
M. F. C16H13FeP Telephone 1-800-521-8956
M. W. 292.093181 Fax
Purity 97% Email
Storage Chembase ID: 151706

SYNONYMS

Title
1,1′-双(苯基亚膦基)二茂铁
IUPAC name
λ2-iron(2+) ion 3-[cyclopenta-1,4-dien-3-id-1-yl(phenyl)phosphanyl]cyclopenta-2,4-dien-1-ide
IUPAC Traditional name
λ2-iron(2+) ion 3-[cyclopenta-1,4-dien-3-id-1-yl(phenyl)phosphanyl]cyclopenta-2,4-dien-1-ide
Synonyms
1,1′-(Ferrocenediyl)phenylphosphine
1,1′-(二茂铁二基)苯膦

DATABASE IDS

CAS Number 72954-06-4
PubChem SID 24880349
MDL Number MFCD04974069

PROPERTIES

Linear Formula C5H4PC6H5C5H4Fe
Purity 97%
Melting Point 88-92 °C(lit.)
MSDS Link Download
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Storage Temperature 2-8°C
German water hazard class 3

DETAILS

Description (English)
Packaging
1 g in glass bottle
Application
Reactant for:
• Preparation of macrocyclic tridentate ferrocenylphosphine ligands1
• Preparation of phosphorus-bridged ferrocenophane with syn and anti conformations2
• Reaction with phenyllithium and chlorophosphine to give ferrocenediyl ligand and its rhodium complex catalyst for selective hydroformylation of alkenes3
• Ring-opening reactions via ring slippage4
• Preparation of palladium chloro (ferrocene-bridged)phosphine-phosphonite complex for catalysis of Heck reaction of iodobenzene with Me acrylate5
Description (简体中文)
包装
1 g in glass bottle
Application
Reactant for:
• Preparation of macrocyclic tridentate ferrocenylphosphine ligands1
• Preparation of phosphorus-bridged ferrocenophane with syn and anti conformations2
• Reaction with phenyllithium and chlorophosphine to give ferrocenediyl ligand and its rhodium complex catalyst for selective hydroformylation of alkenes3
• Ring-opening reactions via ring slippage4
• Preparation of palladium chloro (ferrocene-bridged)phosphine-phosphonite complex for catalysis of Heck reaction of iodobenzene with Me acrylate5

REFERENCES