1,1′-Bis(phenylphosphinidene)ferrocene

• Catalog No.: 567159
• CAS Number: 72954-06-4
• M. F.: C16H13FeP
• M. W.: 292.093181
• Purity: 97%

SYNONYMS

• Title: 1,1′-双(苯基亚膦基)二茂铁
• IUPAC name: λ^2-iron(2+) ion 3-[cyclopenta-1,4-dien-3-id-1-yl(phenyl)phosphanyl]cyclopenta-2,4-dien-1-ide
• IUPAC Traditional name: λ^2-iron(2+) ion 3-[cyclopenta-1,4-dien-3-id-1-yl(phenyl)phosphanyl]cyclopenta-2,4-dien-1-ide
• Synonyms: 1,1′-(Ferrocenediyl)phenylphosphine; 1,1′-(二茂铁二基)苯膦

DATABASE IDS

• CAS Number: 72954-06-4
• PubChem SID: 24880349
• MDL Number: MFCD04974069

PROPERTIES

• Linear Formula: C5H4PC6H5C5H4Fe
• Purity: 97%
• Melting Point: 88-92 °C(lit.)
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• Storage Temperature: 2-8°C
• German water hazard class: 3

DETAILS

Description (English)

Packaging
1 g in glass bottle
Application
Reactant for:
• Preparation of macrocyclic tridentate ferrocenylphosphine ligands1
• Preparation of phosphorus-bridged ferrocenophane with syn and anti conformations2
• Reaction with phenyllithium and chlorophosphine to give ferrocenediyl ligand and its rhodium complex catalyst for selective hydroformylation of alkenes3
• Ring-opening reactions via ring slippage4
• Preparation of palladium chloro (ferrocene-bridged)phosphine-phosphonite complex for catalysis of Heck reaction of iodobenzene with Me acrylate5

Description (简体中文)

包装
1 g in glass bottle
Application
Reactant for:
• Preparation of macrocyclic tridentate ferrocenylphosphine ligands1
• Preparation of phosphorus-bridged ferrocenophane with syn and anti conformations2
• Reaction with phenyllithium and chlorophosphine to give ferrocenediyl ligand and its rhodium complex catalyst for selective hydroformylation of alkenes3
• Ring-opening reactions via ring slippage4
• Preparation of palladium chloro (ferrocene-bridged)phosphine-phosphonite complex for catalysis of Heck reaction of iodobenzene with Me acrylate5