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Bromobis(dimethylamino)borane

Catalog No. 476668 Name Sigma Aldrich
CAS Number 6990-27-8 Website http://www.sigmaaldrich.com
M. F. C4H12BBrN2 Telephone 1-800-521-8956
M. W. 178.86648 Fax
Purity 97% Email
Storage Chembase ID: 151576

SYNONYMS

Title
双(二甲氨基)硼烷溴
IUPAC name
[bromo(dimethylamino)boranyl]dimethylamine
IUPAC Traditional name
[bromo(dimethylamino)boranyl]dimethylamine
Synonyms
1-Bromo-N,N,N′,N′-tetramethylboranediamine

DATABASE IDS

PubChem SID 24871286
CAS Number 6990-27-8
MDL Number MFCD00464744

PROPERTIES

Linear Formula [(CH3)2N]2BBr
Purity 97%
Boiling Point 20-28 °C/0.5 mmHg(lit.)
Density 1.259 g/mL at 25 °C(lit.)
Flash Point 53 °C
Flash Point 127.4 °F
Refractive Index n20/D 1.478(lit.)
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Signal Word Danger
GHS Hazard statements H226-H260-H314
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P223-P231 + P232-P280-P305 + P351 + P338-P370 + P378-P422
RID/ADR UN 3398 4.3/PG 1
Risk Statements 10-14-34
Safety Statements 16-26-36/37/39-45
Supplemental Hazard Statements Reacts violently with water.
Hazard Class 4.3
UN Number 3398
Packing Group 1
German water hazard class 3

DETAILS

Description (English)
Packaging
10 mL in glass bottle
Application
Reactant involved in:
• Intramolecular cyclization1
• Oxidative addition for synthesis of platinum boryl phosphine bromo complexes2
• Synthesis of fluorenyltripyrazolylborate ligands3
• Preparation of rigid-backbone conjugated polymers4
• Conversion of epoxides to halohydrins5
Description (简体中文)
包装
10 mL in glass bottle
Application
Reactant involved in:
• Intramolecular cyclization1
• Oxidative addition for synthesis of platinum boryl phosphine bromo complexes2
• Synthesis of fluorenyltripyrazolylborate ligands3
• Preparation of rigid-backbone conjugated polymers4
• Conversion of epoxides to halohydrins5

REFERENCES