1,1′-Bis(diphenylphosphino)ferrocene

• Catalog No.: 177261
• CAS Number: 12150-46-8
• M. F.: C34H28FeP2
• M. W.: 554.378642
• Purity: 97%

SYNONYMS

• Title: 1,1′-双(二苯基膦)二茂铁
• IUPAC name: λ^2-iron(2+) ion bis(3-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide)
• IUPAC Traditional name: λ^2-iron(2+) ion bis(3-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide)
• Synonyms: 1,1′-二茂铁二基-双(二苯基膦); dppf; 1,1′-Ferrocenediyl-bis(diphenylphosphine)

DATABASE IDS

• CAS Number: 12150-46-8
• PubChem SID: 24850625
• MDL Number: MFCD00001422

PROPERTIES

• Empirical Formula (Hill Notation): C34H28FeP2
• Purity: 97%
• Ligand For: Buchwald-Hartwig Cross Coupling Reaction
• Ligand For: Carbonylations
• Ligand For: Ene Reaction
• Ligand For: Heck Reaction
• Ligand For: Negishi Coupling
• Ligand For: Sonogashira Coupling
• Ligand For: Stille Coupling
• Ligand For: Suzuki-Miyaura Coupling
• Ligand For: Tsuji-Trost Reaction
• Melting Point: 181-182 °C (dec.)(lit.)
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• German water hazard class: 3

DETAILS

Description (English)

Application
Ligand used in a Pd(II)-catalyzed cross-coupling synthesis of oxazepine ring systems.1
General description
Novel functionalized furan derivatives were prepared via Pd-phosphine sequential C-C and C-O bond formation.2
Packaging
1, 10, 25 g in glass bottle

Description (简体中文)

Application
用作 Pd(II) 催化的交叉偶联反应合成氧氮杂卓环体系的配体。1
General description
通过钯-膦催化的 C-C 和 C-O 键顺序成键反应制备新型官能化呋喃衍生物。2
包装
1, 10, 25 g in glass bottle