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(Triphenylphosphine)copper hydride hexamer_Molecular_structure_CAS_33636-93-0)
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(Triphenylphosphine)copper hydride hexamer

Catalog No. 364975 Name Sigma Aldrich
CAS Number 33636-93-0 Website http://www.sigmaaldrich.com
M. F. C108H90Cu6P6 Telephone 1-800-521-8956
M. W. 1954.988766 Fax
Purity 90% Email
Storage Chembase ID: 129635

SYNONYMS

Title
三苯基膦-氢化铜六聚物
IUPAC name
hexakis(triphenylphosphane) hexakis(λ1-copper)
IUPAC Traditional name
hexakis(triphenylphosphine) hexakis(λ1-copper)
Synonyms
Stryker’s reagent
Cuprous hydride triphenylphosphine hexamer
Hydrido(triphenylphosphine)copper(I) hexamer
Triphenylphosphine-Copper(I) hydride Hexamer
Stryker 试剂
三苯基磷酸亚酮六聚体

DATABASE IDS

PubChem SID 24862472
CAS Number 33636-93-0
MDL Number MFCD00221518

PROPERTIES

Linear Formula [(C6H5)3PCuH]6
Purity 90%
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 36/37/38
Safety Statements 26-36
German water hazard class 3

DETAILS

Description (English)
Packaging
1, 5 g in glass bottle
Application
Catalyst for:
• Conjugate reduction of ortho-substituted cinnamic esters to form copper enolates1
• Chemoselective preparation of alcohols via hydrogenation of aldehydes2
• 1,2-addition/transmetalation reactions3
• Synthesis of monomer for preparation of phosphorus- and silicon-containing epoxy resins4
• Hydrosilylation reactions5
• Chiral hydrogenation reactions6
• Hydrostannation of activated alkynes7
Useful synthetic applications include stoichiometric and catalytic hydrogenations, chemoselective conjugate reductions, as well as regiospecific and stereoselectiveconjugate hydride reductions.
Description (简体中文)
包装
1, 5 g in glass bottle
Application
Catalyst for:
• Conjugate reduction of ortho-substituted cinnamic esters to form copper enolates1
• Chemoselective preparation of alcohols via hydrogenation of aldehydes2
• 1,2-addition/transmetalation reactions3
• Synthesis of monomer for preparation of phosphorus- and silicon-containing epoxy resins4
• Hydrosilylation reactions5
• Chiral hydrogenation reactions6
• Hydrostannation of activated alkynes7
可用于合成用途包括化学计量和催化氢化反应、化学选择共轭还原以及区域专一和立体选择共轭氢化物还原反应。

REFERENCES