(Triphenylphosphine)copper hydride hexamer

• Catalog No.: 364975
• CAS Number: 33636-93-0
• M. F.: C108H90Cu6P6
• M. W.: 1954.988766
• Purity: 90%

SYNONYMS

• Title: 三苯基膦-氢化铜六聚物
• IUPAC name: hexakis(triphenylphosphane) hexakis(λ^1-copper)
• IUPAC Traditional name: hexakis(triphenylphosphine) hexakis(λ^1-copper)
• Synonyms: Stryker’s reagent; Cuprous hydride triphenylphosphine hexamer; Hydrido(triphenylphosphine)copper(I) hexamer; Triphenylphosphine-Copper(I) hydride Hexamer; Stryker 试剂; 三苯基磷酸亚酮六聚体

DATABASE IDS

• PubChem SID: 24862472
• CAS Number: 33636-93-0
• MDL Number: MFCD00221518

PROPERTIES

• Linear Formula: [(C6H5)3PCuH]6
• Purity: 90%
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 36/37/38
• Safety Statements: 26-36
• German water hazard class: 3

DETAILS

Description (English)

Packaging
1, 5 g in glass bottle
Application
Catalyst for:
• Conjugate reduction of ortho-substituted cinnamic esters to form copper enolates1
• Chemoselective preparation of alcohols via hydrogenation of aldehydes2
• 1,2-addition/transmetalation reactions3
• Synthesis of monomer for preparation of phosphorus- and silicon-containing epoxy resins4
• Hydrosilylation reactions5
• Chiral hydrogenation reactions6
• Hydrostannation of activated alkynes7
Useful synthetic applications include stoichiometric and catalytic hydrogenations, chemoselective conjugate reductions, as well as regiospecific and stereoselectiveconjugate hydride reductions.

Description (简体中文)

包装
1, 5 g in glass bottle
Application
Catalyst for:
• Conjugate reduction of ortho-substituted cinnamic esters to form copper enolates1
• Chemoselective preparation of alcohols via hydrogenation of aldehydes2
• 1,2-addition/transmetalation reactions3
• Synthesis of monomer for preparation of phosphorus- and silicon-containing epoxy resins4
• Hydrosilylation reactions5
• Chiral hydrogenation reactions6
• Hydrostannation of activated alkynes7
可用于合成用途包括化学计量和催化氢化反应、化学选择共轭还原以及区域专一和立体选择共轭氢化物还原反应。