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2-(Triphenylphosphoranylidene)propionaldehyde_Molecular_structure_CAS_24720-64-7)
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2-(Triphenylphosphoranylidene)propionaldehyde

Catalog No. 374377 Name Sigma Aldrich
CAS Number 24720-64-7 Website http://www.sigmaaldrich.com
M. F. C21H19OP Telephone 1-800-521-8956
M. W. 318.348721 Fax
Purity 98% Email
Storage Chembase ID: 151423

SYNONYMS

Title
2-(三苯基正膦基)丙醛
IUPAC name
2-(triphenyl-λ5-phosphanylidene)propanal
IUPAC Traditional name
2-(triphenyl-λ5-phosphanylidene)propanal
Synonyms
1-Formylethylidenetriphenylphosphorane

DATABASE IDS

CAS Number 24720-64-7
PubChem SID 24863304
MDL Number MFCD00075596

PROPERTIES

Linear Formula (C6H5)3P=C(CH3)CHO
Purity 98%
Melting Point 219-221 °C(lit.)
MSDS Link Download
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
German water hazard class 3

DETAILS

Description (English)
Packaging
1, 10 g in glass bottle
Application
Reactant for:
• Preparation of acitretin analogs with antitumor activity1
• Stereoselective synthesis of essential building blocks of phorboxazole A via hetero Diels-Alder and stereoselective hetero-Michael addition/equilibration2
• Preparation of C1-C14 fragment of sarcoglaucol-16-one via Z-selective ando-type Horner-Wadsworth-Emmons olefination3
• Wittig reactions4
• Synthesis of ring-expanded and epothilone-hybridized macrosphelide analogs as apoptosis-inducing agents5
• Preparation of phosphonic acid-containing analogs of mycophenolic acid as inhibitors of IMPDH6
Description (简体中文)
包装
1, 10 g in glass bottle
Application
Reactant for:
• Preparation of acitretin analogs with antitumor activity1
• Stereoselective synthesis of essential building blocks of phorboxazole A via hetero Diels-Alder and stereoselective hetero-Michael addition/equilibration2
• Preparation of C1-C14 fragment of sarcoglaucol-16-one via Z-selective ando-type Horner-Wadsworth-Emmons olefination3
• Wittig reactions4
• Synthesis of ring-expanded and epothilone-hybridized macrosphelide analogs as apoptosis-inducing agents5
• Preparation of phosphonic acid-containing analogs of mycophenolic acid as inhibitors of IMPDH6

REFERENCES