N-Benzylcinchoninium chloride

• Catalog No.: 366188
• CAS Number: 69221-14-3
• M. F.: C26H29ClN2O
• M. W.: 420.97426
• Purity: 98%

SYNONYMS

• Title: N-苄基氯化辛可宁
• IUPAC name: (2R,4S,5R)-1-benzyl-5-ethenyl-2-[(S)-hydroxy(quinolin-4-yl)methyl]-1-azabicyclo[2.2.2]octan-1-ium chloride
• IUPAC Traditional name: (2R,4S,5R)-1-benzyl-5-ethenyl-2-[(S)-hydroxy(quinolin-4-yl)methyl]-1-azabicyclo[2.2.2]octan-1-ium chloride
• Synonyms: BCNC; 9-Hydroxy-1-(phenylmethyl)cinchonanium chloride

DATABASE IDS

• CAS Number: 69221-14-3
• EC Number: 273-915-8
• MDL Number: MFCD00082423
• Beilstein Number: 5232950
• PubChem SID: 24862625

PROPERTIES

• Empirical Formula (Hill Notation): C26H29ClN2O
• Purity: 98%
• Melting Point: 256 °C (dec.)(lit.)
• Optical Rotation: [α]20/D +169°, c = 0.4 in H2O
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 36/37/38
• Safety Statements: 26-36
• German water hazard class: 3

DETAILS

Description (简体中文)

包装
10 g in glass bottle
Application
Phase-transfer catalyst involved in:
• Enantioselective alkylation of malonic diester with alkyl halides1
• Hydrolysis of enol esters2
• Asymmetric 6π electrocyclization for synthesis of functionalized indolines3
• Asymmetric Michael addition4
• Alkylation of monosubstituted indolinones with alkylhalides5
• Asymmetric destruction and kinetic resolution of 1-benzylated Reissert compounds6

Description (English)

Packaging
10 g in glass bottle
Application
Phase-transfer catalyst involved in:
• Enantioselective alkylation of malonic diester with alkyl halides1
• Hydrolysis of enol esters2
• Asymmetric 6π electrocyclization for synthesis of functionalized indolines3
• Asymmetric Michael addition4
• Alkylation of monosubstituted indolinones with alkylhalides5
• Asymmetric destruction and kinetic resolution of 1-benzylated Reissert compounds6