Allyldiphenylphosphine oxide

• Catalog No.: 477966
• CAS Number: 4141-48-4
• M. F.: C15H15OP
• M. W.: 242.252761
• Purity: 97%

SYNONYMS

• Title: 烯丙基联苯氧化膦
• IUPAC name: [phenyl(prop-2-en-1-yl)phosphoroso]benzene
• IUPAC Traditional name: [phenyl(prop-2-en-1-yl)phosphoroso]benzene
• Synonyms: NSC 616249; NSC 98715; Diphenyl-2-propenylphosphine oxide

DATABASE IDS

• MDL Number: MFCD00013908
• CAS Number: 4141-48-4
• PubChem SID: 24871431

PROPERTIES

• Linear Formula: H2C=CHCH2P(C6H5)2(O)
• Purity: 97%
• Melting Point: 110-114 °C(lit.)
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 36/37/38
• Safety Statements: 26-36
• German water hazard class: 3

DETAILS

Description (English)

Packaging
10 g in glass bottle
Application
Reactant for:
• Preparaton of a-substituted alkylsilanes via regio- and chemoselective copper-catalyzed silylzincation and electrophilic substitution from terminal alkenes, and prepn. of α-substituted alcohols via Fleming-Tamao oxidation of alkylsilanes1
• Olefin isomerization with Grubbs′ catalysts occluded in a hydrophobic matrix of polydimethylsiloxane (PDMS)2
• C9-substituted trans-hydrindene via diastereotopic group-selective intramolecular Diels-Alder reaction3
• Isomerization of allyl group-containing compounds to propenyl group-containing compounds in the presence of a Grubbs second-generation Ru catalyst4
• Ruthenium-catalyzed olefin cross-metathesis of vinyl and allyl phosphine oxides to give alkenyl phosphine oxides and bis-phosphine oxides5

Description (简体中文)

包装
10 g in glass bottle
Application
Reactant for:
• Preparaton of a-substituted alkylsilanes via regio- and chemoselective copper-catalyzed silylzincation and electrophilic substitution from terminal alkenes, and prepn. of α-substituted alcohols via Fleming-Tamao oxidation of alkylsilanes1
• Olefin isomerization with Grubbs′ catalysts occluded in a hydrophobic matrix of polydimethylsiloxane (PDMS)2
• C9-substituted trans-hydrindene via diastereotopic group-selective intramolecular Diels-Alder reaction3
• Isomerization of allyl group-containing compounds to propenyl group-containing compounds in the presence of a Grubbs second-generation Ru catalyst4
• Ruthenium-catalyzed olefin cross-metathesis of vinyl and allyl phosphine oxides to give alkenyl phosphine oxides and bis-phosphine oxides5