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1-Propynylmagnesium bromide solution_Molecular_structure_CAS_16466-97-0)
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1-Propynylmagnesium bromide solution

Catalog No. 429007 Name Sigma Aldrich
CAS Number 16466-97-0 Website http://www.sigmaaldrich.com
M. F. C3H3BrMg Telephone 1-800-521-8956
M. W. 143.26492 Fax
Purity Email
Storage Chembase ID: 151302

SYNONYMS

Title
1-丙炔溴化镁 溶液
IUPAC name
bromo(prop-1-yn-1-yl)magnesium
IUPAC Traditional name
bromo(prop-1-yn-1-yl)magnesium

DATABASE IDS

PubChem SID 24866829
MDL Number MFCD00216588
CAS Number 16466-97-0
Beilstein Number 3929146

PROPERTIES

Concentration 0.5 M in THF
Linear Formula CH3C≡CMgBr
Boiling Point 65-67 °C
Density 0.941 g/mL at 25 °C
Flash Point -1 °C
Flash Point 30.2 °F
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Pictograms GHS07
GHS Signal Word Danger
GHS Hazard statements H225-H261-H314-H335
European Hazard Symbols Flammable Flammable (F)
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P210-P231 + P232-P261-P280-P305 + P351 + P338-P422
RID/ADR UN 3399 4.3/PG 1
Risk Statements 11-14/15-19-34-37
Safety Statements 16-26-36/37/39-43-45
Storage Temperature 2-8°C
Supplemental Hazard Statements May form explosive peroxides., Reacts violently with water.
Hazard Class 4.3
UN Number 3399
Packing Group 1
German water hazard class 3

DETAILS

Description (English)
Application
Preparation of hydroxy enynes which underwent gold(I)-catalyzed benzannulation leading to tetrahydronaphthalenes.1
Packaging
100, 800 mL in Sure/Seal™
Description (简体中文)
Application
制备羟基烯炔,该羟基烯炔经金(I)-催化的苯环化反应可生成四氢化萘。1
包装
100, 800 mL in Sure/Seal™

REFERENCES