o-Phenylene phosphorochloridite

• Catalog No.: 155764
• CAS Number: 1641-40-3
• M. F.: C6H4ClO2P
• M. W.: 174.521521
• Purity: 97%

SYNONYMS

• Title: 1,2-亚苯基-次氯酸化膦
• IUPAC name: 2-chloro-2H-1,3,2-benzodioxaphosphole
• IUPAC Traditional name: 2-chloro-1,3,2-benzodioxaphosphole
• Synonyms: Cyclic o-phenylene phosphorochloridite; Phosphorochloridous acid orthophenylene ester; 2-Chloro-1,3,2-benzodioxaphosphole; 2-氯-1,3,2-苯并二氧环磷烯; o-Phenylene chlorophosphite; Chloro(1,2-phenylenedioxy)phosphine; Pyrocatechol phosphoryl chloride

DATABASE IDS

• MDL Number: MFCD00005853
• PubChem SID: 24849564
• CAS Number: 1641-40-3
• EC Number: 216-690-3
• Beilstein Number: 135455

PROPERTIES

• Empirical Formula (Hill Notation): C6H4ClO2P
• Purity: 97%
• Boiling Point: 80 °C/20 mmHg(lit.)
• Density: 1.466 g/mL at 25 °C(lit.)
• Flash Point: 110 °C
• Flash Point: 230 °F
• Melting Point: 30-35 °C(lit.)
• Refractive Index: n20/D 1.571(lit.)
• GHS Signal Word: Danger
• GHS Hazard statements: H314
• European Hazard Symbols: Corrosive (C)
• Personal Protective Equipment: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• GHS Precautionary statements: P280-P305 + P351 + P338-P310
• RID/ADR: UN 3261 8/PG 2
• Risk Statements: 34
• Safety Statements: 26-36/37/39-45
• Hazard Class: 8
• UN Number: 3261
• Packing Group: 2
• German water hazard class: 3

DETAILS

Description (English)

Packaging
10 g in glass bottle
Application

• Catalyst in synthesis of bakkane sesquiterpenes1
• Reactant in reversible halogen-halogen ligand substitution at room temperature, and in irreversible halogen-O substitution at higher temperatures2
• Reactant in preparation of gold(I) trimethoxybenzonitrile phosphine isolated precatalysts3
• Reactant for preparation of pyrroles by TMSOTf-catalyzed Arbuzov reaction4
• Phosphorylation agent5
• Reactant for reparation of vinyl-substituted spirophosphoranes and vinylphosphonates via Markovnikov addition6

Description (简体中文)

包装
10 g in glass bottle
Application

• Catalyst in synthesis of bakkane sesquiterpenes1
• Reactant in reversible halogen-halogen ligand substitution at room temperature, and in irreversible halogen-O substitution at higher temperatures2
• Reactant in preparation of gold(I) trimethoxybenzonitrile phosphine isolated precatalysts3
• Reactant for preparation of pyrroles by TMSOTf-catalyzed Arbuzov reaction4
• Phosphorylation agent5
• Reactant for reparation of vinyl-substituted spirophosphoranes and vinylphosphonates via Markovnikov addition6