1,1′-(Azodicarbonyl)dipiperidine

• Catalog No.: 255920
• CAS Number: 10465-81-3
• M. F.: C12H20N4O2
• M. W.: 252.3128
• Purity: 99%

SYNONYMS

• Title: 1,1'-(偶氮二羰基)二哌啶
• IUPAC name: N-[(piperidine-1-carbonyl)imino]piperidine-1-carboxamide
• IUPAC Traditional name: N-(piperidine-1-carbonylimino)piperidine-1-carboxamide
• Synonyms: 1,1′-Azobis(N,N-pentamethyleneformamide); 偶氮二甲酰二哌啶; SR 4077; NSC 356027; ADD; Azodicarboxylic acid dipiperidide

DATABASE IDS

• Beilstein Number: 261917
• PubChem SID: 24855495
• MDL Number: MFCD00010111
• CAS Number: 10465-81-3

PROPERTIES

• Empirical Formula (Hill Notation): C12H20N4O2
• Purity: 99%
• Melting Point: 134-136 °C(lit.)
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 36/37/38
• Safety Statements: 26-36
• German water hazard class: 3

DETAILS

Description (English)

Application
Used in a study of the copper-catalyzed addition of aryboronic acids to azodicarboxyl derivatives providing aryl-substituted hydrazides.10
Widely used reagent for the Mitsunobu reaction
Reactant for preparation of:
• Polyfluoroalkylated tripyrazolylmethane ligands1
• (-)-Hygromycin A via Mitsunobu glycosylation2
• Optically active α,α-disubstituted amino acids via Mitsunobu reaction3
• Aza-β-lactams through [2+2] cycloaddition reactions4
• Glycosyl disulfides5
• Pyridine ether PPAR agonists6
• S-glycosyl amino acid building blocks for combinatorial neoglycopeptide synthesis7
• Histamine H3 receptor antagonists8Reactant for:
• Mitsunobu inversion reactions9
Packaging
25 g in poly bottle
5 g in glass bottle

Description (简体中文)

Application
广泛用于 Mitsunobu 反应的试剂
用于研究芳基硼酸通过铜催化加成得到偶氮二甲酸衍生物，从而生成芳基取代酰肼的反应。10
Reactant for preparation of:
• Polyfluoroalkylated tripyrazolylmethane ligands1
• (-)-Hygromycin A via Mitsunobu glycosylation2
• Optically active α,α-disubstituted amino acids via Mitsunobu reaction3
• Aza-β-lactams through [2+2] cycloaddition reactions4
• Glycosyl disulfides5
• Pyridine ether PPAR agonists6
• S-glycosyl amino acid building blocks for combinatorial neoglycopeptide synthesis7
• Histamine H3 receptor antagonists8Reactant for:
• Mitsunobu inversion reactions9
包装
25 g in poly bottle
5 g in glass bottle