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S-Alpine-Borane® solution_Molecular_structure_CAS_42371-63-1)
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S-Alpine-Borane® solution

Catalog No. 237701 Name Sigma Aldrich
CAS Number 42371-63-1 Website http://www.sigmaaldrich.com
M. F. C18H31B Telephone 1-800-521-8956
M. W. 258.24974 Fax
Purity Email
Storage Chembase ID: 137458

SYNONYMS

Title
S-Alpine-Borane® 溶液
IUPAC name
(1s,5s)-9-[(1S,2R,3S,5S)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl]-9-borabicyclo[3.3.1]nonane
IUPAC Traditional name
(1s,5s)-9-[(1S,2R,3S,5S)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl]-9-borabicyclo[3.3.1]nonane
Synonyms
B-Isopinocampheyl-9-borabicyclo[3.3.1]nonane
B-异松蒎基-9-硼二环[3.3.1]壬烷

DATABASE IDS

MDL Number MFCD00082390
CAS Number 42371-63-1
PubChem SID 24854265

PROPERTIES

Concentration 0.5 M in THF
Empirical Formula (Hill Notation) C18H31B
Density 0.897 g/mL at 25 °C
Flash Point -17 °C
Flash Point 1.4 °F
Optical Rotation [α]22/D +1.2°, neat
GHS Pictograms GHS02
GHS Pictograms GHS07
GHS Signal Word Danger
GHS Hazard statements H225-H250-H319-H335
European Hazard Symbols Flammable Flammable (F)
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P210-P222-P231-P261-P305 + P351 + P338-P422
RID/ADR UN 1993 3/PG 2
Risk Statements 11-19-36/37
Safety Statements 16-26
Supplemental Hazard Statements May form explosive peroxides.
Hazard Class 3
UN Number 1993
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Packaging
100, 800 mL in Sure/Seal™
Application
R- and S-Alpine-Boranes are used for asymmetric reduction of aldehydes1,2 and prochiral ketones.3,4,2
Legal Information
Alpine-Borane is a registered trademark of Sigma-Aldrich Co. LLC
Description (简体中文)
包装
100, 800 mL in Sure/Seal™
Application
R- 和 S-Alpine-Boranes 用于醛1,2和前手性酮的不对称还原反应。3,4,2
法律信息
Alpine-Borane 注册商标 Sigma-Aldrich Co. LLC

REFERENCES