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4-Pentenoyl chloride_Molecular_structure_CAS_39716-58-0)
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4-Pentenoyl chloride

Catalog No. 468479 Name Sigma Aldrich
CAS Number 39716-58-0 Website http://www.sigmaaldrich.com
M. F. C5H7ClO Telephone 1-800-521-8956
M. W. 118.56148 Fax
Purity 98% Email
Storage Chembase ID: 151153

SYNONYMS

Title
4-戊烯酰氯
IUPAC name
pent-4-enoyl chloride
IUPAC Traditional name
pent-4-enoyl chloride

DATABASE IDS

CAS Number 39716-58-0
PubChem SID 24870517
MDL Number MFCD00799572

PROPERTIES

Linear Formula H2C=CHCH2CH2COCl
Purity 98%
Boiling Point 125 °C(lit.)
Density 1.074 g/mL at 25 °C(lit.)
Flash Point 27 °C
Flash Point 80.6 °F
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Signal Word Danger
GHS Hazard statements H226-H314
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P280-P305 + P351 + P338-P310
RID/ADR UN 2920 8/PG 2
Risk Statements 10-34
Safety Statements 16-26-27-36/37/39-45
Hazard Class 8
UN Number 2920
Packing Group 2
German water hazard class 1

DETAILS

Description (English)
Application
Used in the preparation of an acyclic tripeptide containing a heterochiral D-pro-L-pro template with a propensity to exist as a 310 helical conformation. Cyclization via olefin metathesis (Grubbs Catalyst) provides the coresponding tetrapeptide without disruption of the helical conformation.1
Packaging
5, 25 mL in glass bottle
Description (简体中文)
Application
用于制备含左右异向 D-pro-L-pro 模板的无环三肽,该模板倾向于以 310 螺旋构象的形式存在。通过烯烃复分解进行的环化反应(Grubbs 催化剂)可在不破环螺旋构象的情况下生成对应的四肽。1
包装
5, 25 mL in glass bottle

REFERENCES