o-Tolylboronic acid

• Catalog No.: 393606
• CAS Number: 16419-60-6
• M. F.: C7H9BO2
• M. W.: 135.95616
• Purity: ≥95.0%

SYNONYMS

• Title: 邻甲基苯硼酸
• IUPAC name: (2-methylphenyl)boronic acid
• IUPAC Traditional name: 2-methylphenylboronic acid
• Synonyms: 2-Methylbenzeneboronic acid; o-Boronotoluene; 2-Tolueneboronic acid; o-Methylphenylboronic acid; 2-Methylphenylboronic acid; (2-Tolyl)boronic acid; 2-Methyl-1-phenylboronic acid; o-Tolueneboronic acid; 2-甲基苯硼酸

DATABASE IDS

• CAS Number: 16419-60-6
• PubChem SID: 24864527
• MDL Number: MFCD00093526

PROPERTIES

• Linear Formula: CH3C6H4B(OH)2
• Purity: ≥95.0%
• Melting Point: 162-164 °C(lit.)
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 36/37/38
• Safety Statements: 26-36
• German water hazard class: 3

DETAILS

Description (English)

Other Notes
Contains varying amounts of anhydride
Packaging
1, 5, 25 g in glass bottle
Application
Reagent used for
• Palladium-catalyzed direct arylation of pyrazoles with phenylboronic acids1
• Pd-catalyzed arylation using Suzuki-Miyaura cross-coupling in water2
• Ruthenium catalyzed direct arylation reactions3
• Ligand-free copper-catalyzed coupling reactions4
• Copper-catalyzed cross-coupling reactions of diaryl diselenides5
• Phosphine-free Suzuki-Miyaura cross-coupling reactions6
• Rhodium-catalyzed asymmetric 1,4-addition reactions7 Reagent used in Preparation of
• Chiral monophosphorus ligands in asymmetric Suzuki-Miyaura coupling reaction8
• Palladium nanoparticles immobilized by click ionic copolymers as recyclable catalysts for Suzuki-Miyaura cross-coupling reaction in water9
• Human farnesyl pyrophosphate synthase inhibitors as antitumor agents for multiple myeloma cells10

Description (简体中文)

Other Notes
含有不定量的酸酐
包装
1, 5, 25 g in glass bottle
Application
Reagent used for
• Palladium-catalyzed direct arylation of pyrazoles with phenylboronic acids1
• Pd-catalyzed arylation using Suzuki-Miyaura cross-coupling in water2
• Ruthenium catalyzed direct arylation reactions3
• Ligand-free copper-catalyzed coupling reactions4
• Copper-catalyzed cross-coupling reactions of diaryl diselenides5
• Phosphine-free Suzuki-Miyaura cross-coupling reactions6
• Rhodium-catalyzed asymmetric 1,4-addition reactions7 Reagent used in Preparation of
• Chiral monophosphorus ligands in asymmetric Suzuki-Miyaura coupling reaction8
• Palladium nanoparticles immobilized by click ionic copolymers as recyclable catalysts for Suzuki-Miyaura cross-coupling reaction in water9
• Human farnesyl pyrophosphate synthase inhibitors as antitumor agents for multiple myeloma cells10