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(S)-(+)-1,2-Isopropylideneglycerol_Molecular_structure_CAS_22323-82-6)
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(S)-(+)-1,2-Isopropylideneglycerol

Catalog No. 237744 Name Sigma Aldrich
CAS Number 22323-82-6 Website http://www.sigmaaldrich.com
M. F. C6H12O3 Telephone 1-800-521-8956
M. W. 132.15768 Fax
Purity 98% Email
Storage Chembase ID: 88147

SYNONYMS

Title
(S)-(+)-1,2-异亚丙基甘油
IUPAC name
[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]methanol
IUPAC Traditional name
[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]methanol
Synonyms
D-α,β-异亚丙基甘油
D-α,β-Isopropylideneglycerol
(S)-(+)-2,2-二甲基-1,3-二氧戊环-4-甲醇
1,2-Isopropylidene-sn-glycerol
D-(+)-Solketal
D-(+)-丙酮缩甘油
D-1,2-O-isopropylidene-sn-glycerol
(S)-(+)-2,2-Dimethyl-1,3-dioxolane-4-methanol

DATABASE IDS

Beilstein Number 80118
PubChem SID 24854267
CAS Number 22323-82-6
EC Number 244-910-8
MDL Number MFCD00063239

PROPERTIES

Empirical Formula (Hill Notation) C6H12O3
Optical Purity ee: 99% (GLC)
Purity 98%
Boiling Point 82-83 °C/14 mmHg(lit.)
Density 1.07 g/mL at 25 °C(lit.)
Flash Point 90 °C
Flash Point 194 °F
Optical Rotation [α]20/D +13.5°, neat
Refractive Index n20/D 1.434(lit.)
MSDS Link Download
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Storage Temperature 2-8°C
German water hazard class 3

DETAILS

Description (English)
Application
Used in a synthesis of a chiral allylic triol via extrusion of SO2 from an α,β-epoxysulfone.1
Packaging
1, 5 g in glass bottle
Description (简体中文)
Application
用于由 α,β-环氧砜通过 SO2 脱去反应合成手性烯丙基三醇。1
包装
1, 5 g in glass bottle

REFERENCES