(Trimethylsilyl)methylmagnesium chloride solution

• Catalog No.: 256021
• CAS Number: 13170-43-9
• M. F.: C4H11ClMgSi
• M. W.: 146.97364

SYNONYMS

• Title: (三甲基硅基)甲基氯化镁 溶液
• IUPAC name: [(chloromagnesio)methyl]trimethylsilane
• IUPAC Traditional name: [(chloromagnesio)methyl]trimethylsilane

DATABASE IDS

• CAS Number: 13170-43-9
• PubChem SID: 24855503
• Beilstein Number: 3587255
• MDL Number: MFCD00009916

PROPERTIES

• Concentration: 1.0 M in diethyl ether
• Linear Formula: (CH3)3SiCH2MgCl
• Density: 0.777 g/mL at 25 °C
• Flash Point: -40 °C
• Flash Point: -40 °F
• GHS Signal Word: Danger
• GHS Hazard statements: H225-H302-H314-H336
• European Hazard Symbols: Flammable (F)
• European Hazard Symbols: Corrosive (C)
• Personal Protective Equipment: Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P210-P261-P280-P305 + P351 + P338-P310
• RID/ADR: UN 3399 4.3/PG 1
• Risk Statements: 11-14-19-22-34-67
• Safety Statements: 16-26-36/37/39-45
• Supplemental Hazard Statements: May form explosive peroxides., Reacts violently with water.
• Hazard Class: 4.3
• UN Number: 3399
• Packing Group: 1
• German water hazard class: 3

DETAILS

Description (English)

Packaging
100 mL in Sure/Seal™
Application
Reagent used in a variety of nickel catalyzed reactions including alkenation of dithioacetals,1 cross-coupling with aryl triflates and carbamates,2 and cross-coupling with vinyl selenides.3

Description (简体中文)

包装
100 mL in Sure/Seal™
Application
各种镍催化反应试剂，包括二硫缩醛的烯化反应、1三氟甲基磺酸芳基酯和氨基甲酸芳基酯的交叉偶联反应2以及乙烯基硒醚的交叉偶联反应。3