(R)-(+)-2-Methyl-2-propanesulfinamide

• Catalog No.: 497401
• CAS Number: 196929-78-9
• M. F.: C4H11NOS
• M. W.: 121.20124
• Purity: 98%

SYNONYMS

• Title: (R)-(+)-2-甲基-2-丙烷亚磺酰胺
• IUPAC name: (R)-2-methylpropane-2-sulfinamide
• IUPAC Traditional name: (R)-2-methylpropane-2-sulfinamide

DATABASE IDS

• MDL Number: MFCD05861479
• CAS Number: 196929-78-9
• PubChem SID: 24873117

PROPERTIES

• Linear Formula: (CH3)3CS(O)NH2
• Purity: 98%
• Melting Point: 103-107 °C(lit.)
• Optical Rotation: [α]20/D +4°, c = 1.0242 in chloroform stab. with amylenes
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• Storage Temperature: 2-8°C
• German water hazard class: 3

DETAILS

Description (English)

Application
Can be readily transformed into P,N-sulfinyl imine ligands through condensation with aldehydes and ketones, which can undergo iridium-catalyzed asymmetric hydrogenation of olefins.1
Preparation of β-chloro sulfinamides in a synthesis of chiral azridines. Also used to prepare an organocatalyst for enantioselective reduction of imines.
Useful reagent for synthesizing chiral amines.
Ellman′s Sulfinamides
Packaging
1, 5 g in glass bottle
25 g in poly bottle

Description (简体中文)

Application
合成手性胺的有效试剂。
在手性氮丙啶的合成中制备 β-氯代亚磺酰胺。也可用于制备亚胺对映选择性还原反应的有机催化剂。
易与醛和酮发生缩合反应，转化为 P,N-亚磺酰亚胺配体，该配体可参与烯烃的铱催化不对称氢化反应。1
Ellman′s Sulfinamides
包装
1, 5 g in glass bottle
25 g in poly bottle