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Borane tert-butylamine complex_Molecular_structure_CAS_7337-45-3)
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Borane tert-butylamine complex

Catalog No. 180211 Name Sigma Aldrich
CAS Number 7337-45-3 Website http://www.sigmaaldrich.com
M. F. C4H14BN Telephone 1-800-521-8956
M. W. 86.97166 Fax
Purity 97% Email
Storage Chembase ID: 137736

SYNONYMS

Title
甲硼烷-叔丁胺络合物
IUPAC name
2-methylpropan-2-amine borane
IUPAC Traditional name
erbumine borane
Synonyms
叔丁基胺硼烷
NSC 114045
Trihydro(2-methyl-2-propanamine) boron
tert-Butylamine borane

DATABASE IDS

MDL Number MFCD00075635
CAS Number 7337-45-3
PubChem SID 24850855
EC Number 230-851-5

PROPERTIES

Linear Formula (CH3)3CNH2 · BH3
Purity 97%
Apperance powder
Melting Point 98-100 °C (dec.)(lit.)
GHS Pictograms GHS06
GHS Signal Word Danger
GHS Hazard statements H301-H311-H315-H319-H335
European Hazard Symbols Toxic Toxic (T)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
GHS Precautionary statements P261-P280-P301 + P310-P305 + P351 + P338-P312
RID/ADR UN 2811 6.1/PG 3
Risk Statements 21-25-36/37/38
RTECS EO3900000
Safety Statements 26-36/37-45
Hazard Class 6.1
UN Number 2811
Packing Group 3
German water hazard class 3

DETAILS

Description (English)
Packaging
25, 100 g in glass bottle
Application
Reactant involved in:
• Non-destructive analyses and conservation treatments of Indian drawings1
• Dehydrogenation reactions mediated by ruthenium bidentate phosphine complexes2 or ruthenium / iridium bis(N-heterocyclic carbene) complexes3
• The formation of σ-borane complexes4
• Ethanolysis of amine-borane adducts to form a reducing system for transfer hydrogenation of terminal olefins5
• Photochemical hydroboration and oxidation of single-walled carbon nanotubes6
Description (简体中文)
包装
25, 100 g in glass bottle
Application
Reactant involved in:
• Non-destructive analyses and conservation treatments of Indian drawings1
• Dehydrogenation reactions mediated by ruthenium bidentate phosphine complexes2 or ruthenium / iridium bis(N-heterocyclic carbene) complexes3
• The formation of σ-borane complexes4
• Ethanolysis of amine-borane adducts to form a reducing system for transfer hydrogenation of terminal olefins5
• Photochemical hydroboration and oxidation of single-walled carbon nanotubes6

REFERENCES