(-)-Isopinocampheylborane TMEDA complex

• Catalog No.: 251496
• CAS Number: 67826-92-0
• M. F.: C26H54B2N2
• M. W.: 416.34236

SYNONYMS

• Title: (-)-异松蒎基硼烷-四甲基乙二胺络合物
• IUPAC name: bis([(1S,2R,3S,5S)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl]borane); [2-(dimethylamino)ethyl]dimethylamine
• IUPAC Traditional name: bis([(1S,2R,3S,5S)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl]borane); temed
• Synonyms: (-)-N,N′-Bis(monoisopinocampheylborane)-N,N,N′,N′-tetramethylethylenediamine; (-)-N,N′-双(单异松蒎基硼烷)-N,N,N′,N′-四甲基乙二胺; (R)-Alpine-Boramine™

DATABASE IDS

• PubChem SID: 24855135
• CAS Number: 67826-92-0
• MDL Number: MFCD00077801

PROPERTIES

• Empirical Formula (Hill Notation): C13H27BN
• Melting Point: 139-141 °C(lit.)
• GHS Signal Word: Warning
• GHS Hazard statements: H261-H315-H319
• European Hazard Symbols: Flammable (F)
• European Hazard Symbols: Irritant (Xi)
• GHS Precautionary statements: P231 + P232-P305 + P351 + P338-P422
• RID/ADR: UN 2813 4.3/PG 3
• Risk Statements: 15-36/38
• Safety Statements: 26-36-43
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• Hazard Class: 4.3
• UN Number: 2813
• Packing Group: 3
• German water hazard class: 3

DETAILS

Description (English)

Packaging
5 g in glass bottle
Application
Chiral hydroboration reagent.1,2This amine-borane complex has been used as a polarity-reversal catalyst for the kinetic resolution of racemic esters and ketones.3
Legal Information
Alpine-Boramine is a trademark of Sigma-Aldrich Co. LLC

Description (简体中文)

包装
5 g in glass bottle
Application
手性硼氢化反应试剂。1,2该硼烷氨复合物已用作极性倒转催化剂，用于外消旋酯和酮的动力学拆分。3
法律信息
Alpine-Boramine 商标 Sigma-Aldrich Co. LLC