Diisopropyl (ethoxycarbonylmethyl)phosphonate

• Catalog No.: 343560
• CAS Number: 24074-26-8
• M. F.: C10H21O5P
• M. W.: 252.244501
• Purity: 95%

SYNONYMS

• Title: 二异丙基(乙氧基羰甲基)磷酸酯
• IUPAC name: ethyl 2-[bis(propan-2-yloxy)phosphoryl]acetate
• IUPAC Traditional name: ethyl 2-(diisopropoxyphosphoryl)acetate
• Synonyms: Ethyl (diisopropyl phosphono)acetate

DATABASE IDS

• PubChem SID: 24861175
• CAS Number: 24074-26-8
• MDL Number: MFCD00075267

PROPERTIES

• Linear Formula: C2H5O2CCH2P(O)[OCH(CH3)2]2
• Purity: 95%
• Boiling Point: 142-143 °C/11 mmHg(lit.)
• Density: 1.06 g/mL at 25 °C(lit.)
• Flash Point: 113 °C
• Flash Point: 235.4 °F
• Refractive Index: n20/D 1.427(lit.)
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 36/37/38
• Safety Statements: 26-37/39
• German water hazard class: 3

DETAILS

Description (English)

Packaging
5 g in glass bottle
Application
Reactant for:
• Preparation of spiroimine ring fragment of spirolides via stereoselective intermolecular Diels-Alder and aza-Wittig cyclization1
• Katsuki-Sharpless epoxidation reaction2
• Preparation of nine-membered diallylic sulfonamides as chiral building blocks3
• Alpha-phosphono lactams for subsequent Wadsworth-Emmons olefination, and Suzuki coupling reactions to yield diverse pyrrolidinone compounds4
• Synthesis of galactosylceramide analog that induces Th1-biased responses in human (NKT) cells5
• Stereoselective total synthesis of the ionophore antibiotic zincophorin (M144255)6

Description (简体中文)

包装
5 g in glass bottle
Application
Reactant for:
• Preparation of spiroimine ring fragment of spirolides via stereoselective intermolecular Diels-Alder and aza-Wittig cyclization1
• Katsuki-Sharpless epoxidation reaction2
• Preparation of nine-membered diallylic sulfonamides as chiral building blocks3
• Alpha-phosphono lactams for subsequent Wadsworth-Emmons olefination, and Suzuki coupling reactions to yield diverse pyrrolidinone compounds4
• Synthesis of galactosylceramide analog that induces Th1-biased responses in human (NKT) cells5
• Stereoselective total synthesis of the ionophore antibiotic zincophorin (M144255)6