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(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-iridium(I) hexafluorophosphate_Molecular_structure_CAS_64536-78-3)
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(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-iridium(I) hexafluorophosphate

Catalog No. 337498 Name Sigma Aldrich
CAS Number 64536-78-3 Website http://www.sigmaaldrich.com
M. F. C31H50F6IrNP2 Telephone 1-800-521-8956
M. W. 804.8903412 Fax
Purity 85% Email
Storage Chembase ID: 104734

SYNONYMS

Title
1,5-环辛二烯(吡啶)(三环己基磷化氢)铱六氟磷酸盐
IUPAC name
iridium(1+) ion cycloocta-1,5-diene hexafluoro-λ5-phosphanuide pyridine tricyclohexylphosphane
IUPAC Traditional name
iridium(1+) ion 1,5-cyclooctadiene pyridine tricyclohexylphosphine hexafluorophosphate
Synonyms
Crabtree 催化剂
(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-Ir(I) PF6
Iridium(I) hexafluorophosphate (1,5-Cyclooctadiene)-(pyridine)-(tricyclohexylphosphine) complex
铱(I)六氟磷酸(1,5-环辛二烯)-(吡啶)-(三环己基膦)复合物
[Ir(cod)(PCy3)(py)]PF6
Crabtree’s catalyst
六氟磷酸(三环己基膦)(1,5-环辛二烯)(吡啶)合铱

DATABASE IDS

CAS Number 64536-78-3
MDL Number MFCD00075097
PubChem SID 24860483

PROPERTIES

GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 36/37/38
Safety Statements 26-36
German water hazard class 3
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Empirical Formula (Hill Notation) C31H50F6IrNP2
Purity 85%
Melting Point 175 °C (dec.)(lit.)

DETAILS

Description (English)
Application
Catalyst for alkene hydrogenation, isomerization, and hydroboration; also for hydrogen isotope exchange reaction.
Homogeneous hydrogenation catalyst hydroboration catalyst.
Packaging
50, 250 mg in glass bottle
Description (简体中文)
Application
Catalyst for alkene hydrogenation, isomerization, and hydroboration; also for hydrogen isotope exchange reaction.
均相氢化反应催化剂,硼氢化反应催化剂。
包装
50, 250 mg in glass bottle

REFERENCES