Tebbe reagent solution

• Catalog No.: 380237
• CAS Number: 67719-69-1
• M. F.: C13H18AlClTi
• M. W.: 284.583558

SYNONYMS

• Title: TEBBE 试剂 溶液
• IUPAC name: chloro[(dimethylalumanyl)methyl]titaniumbis(ylium); bis(cyclopenta-2,4-dien-1-ide)
• IUPAC Traditional name: chloro[(dimethylalumanyl)methyl]titaniumbis(ylium); bis(cyclopentadienide)
• Synonyms: Bis(cyclopentadienyl)-μ-chloro-(dimethylaluminum)-μ-methylenetitanium; 双(环戊二烯基)-μ-氯化(二甲基铝)-μ-亚甲基钛

DATABASE IDS

• CAS Number: 67719-69-1
• PubChem SID: 24863730
• MDL Number: MFCD00151575

PROPERTIES

• Concentration: 0.5 M in toluene
• Empirical Formula (Hill Notation): C13H18AlClTi
• Density: 0.927 g/mL at 25 °C
• Flash Point: 4 °C
• Flash Point: 39.2 °F
• GHS Signal Word: Danger
• GHS Hazard statements: H225-H304-H314-H336-H361d-H373
• European Hazard Symbols: Flammable (F)
• European Hazard Symbols: Corrosive (C)
• Personal Protective Equipment: Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P210-P261-P280-P301 + P310-P305 + P351 + P338-P310
• RID/ADR: UN 2924 3/PG 2
• Risk Statements: 63-11-34-48/20-65-67
• Safety Statements: 16-26-36/37/39-45-62
• Hazard Class: 3
• UN Number: 2924
• Packing Group: 2
• German water hazard class: 3

DETAILS

Description (English)

Application
A versatile methylenation reagent for the conversion of ketones and aldehydes to olefins, it offers facile reaction with hindered ketones and allows the conversion of esters to vinyl ethers.1
Tebbe reagent can be used to olefinate aldehydes.
Used to methylenate a chiral polyhydroxyketone with high diasteroselctivity.
Packaging
25, 4×25, 100 mL in Sure/Seal™

Description (简体中文)

Application
Tebbe 试剂，可用于醛类的烯化。
用于对手性多羟基酮进行高非对映选择性的亚甲基化。
用于将酮和醛转化为烯烃的多功能亚甲基化试剂，它可与位阻酮进行温顺反应，也可以将酯转化为乙烯醚。1
包装
25, 4×25, 100 mL in Sure/Seal™