K-Selectride® solution

• Catalog No.: 220760
• CAS Number: 54575-49-4
• M. F.: C12H27BK
• M. W.: 221.25208

SYNONYMS

• Title: K-Selectride® 溶液
• IUPAC name: potassium tris(butan-2-yl)boranuide
• IUPAC Traditional name: potassium tris(sec-butyl)boranuide
• Synonyms: 三仲丁基硼氢化钾 溶液; Potassium tri-sec-butylborohydride solution

DATABASE IDS

• MDL Number: MFCD00009324
• PubChem SID: 24853191
• CAS Number: 54575-49-4

PROPERTIES

• Concentration: 1.0 M potassium tri-sec-butylborohydride in THF
• Linear Formula: K[CH(CH3)CH2CH3]3BH
• Density: 0.913 g/mL at 25 °C
• Flash Point: -17 °C
• Flash Point: 1.4 °F
• GHS Signal Word: Danger
• GHS Hazard statements: H225-H260-H314-H335
• European Hazard Symbols: Flammable (F)
• European Hazard Symbols: Corrosive (C)
• Personal Protective Equipment: Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P210-P223-P231 + P232-P261-P370 + P378-P422
• RID/ADR: UN 3399 4.3/PG 1
• Risk Statements: 11-14/15-19-34-37
• Safety Statements: 16-26-36/37/39-43-45
• Supplemental Hazard Statements: May form explosive peroxides., Reacts violently with water.
• Hazard Class: 4.3
• UN Number: 3399
• Packing Group: 1
• German water hazard class: 3

DETAILS

Description (English)

Packaging
100, 800 mL in Sure/Seal™
Application

• Reducing reagent1Reactant for:
• Preparation of a PCP-pincer palladium hydride-K-Selectride complex2
• Formation of P-H, P-C, and C-H bonds by hydride attack3
• Stereoselective conjugate hydride reduction reactions4
Stereoselective reducing agent for ketones. Hydride employed in regioselective reactions with transition metal ligands.
Legal Information
Selectride is a registered trademark of Sigma-Aldrich Co. LLC

Description (简体中文)

包装
100, 800 mL in Sure/Seal™
Application

• Reducing reagent1Reactant for:
• Preparation of a PCP-pincer palladium hydride-K-Selectride complex2
• Formation of P-H, P-C, and C-H bonds by hydride attack3
• Stereoselective conjugate hydride reduction reactions4
酮的立体选择性还原剂。与过渡金属配体发生区域选择性反应的氢化物。
法律信息
Selectride 注册商标 Sigma-Aldrich Co. LLC