N-Methoxy-N-methyl(triphenylphosphoranylidene)acetamide

• Catalog No.: 376876
• CAS Number: 129986-67-0
• M. F.: C22H22NO2P
• M. W.: 363.389341
• Purity: 98%

SYNONYMS

• Title: N-甲氧基-N-甲基(三苯基正膦亚基)乙酰胺
• IUPAC name: N-methoxy-N-methyl-2-(triphenyl-λ^5-phosphanylidene)acetamide
• IUPAC Traditional name: N-methoxy-N-methyl-2-(triphenyl-λ^5-phosphanylidene)acetamide
• Synonyms: (N-Methoxymethylaminocarbonylmethylene)triphenylphosphorane; (N-甲氧基甲基氨基羰基亚甲基)三苯基正膦

DATABASE IDS

• Beilstein Number: 4198472
• PubChem SID: 24863472
• MDL Number: MFCD00134433
• CAS Number: 129986-67-0

PROPERTIES

• Linear Formula: (C6H5)3P=CHCON(OCH3)CH3
• Purity: 98%
• Melting Point: 173-175 °C(lit.)
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 36/37/38
• Safety Statements: 26-36
• German water hazard class: 3

DETAILS

Description (English)

Packaging
5, 25 g in glass bottle
Application
Reactant for:
• Synthesis of electron-deficient alkenes via stereoselective olefination of N-sulfonyl imines1
• Phosphine-catalyzed asymmetric addition reactions2
• Cysteine-catalyzed enantioselective intramolecular Rauhut-Currier reaction3
• Wittig olefination4
• Synthesis of aigialomycin D, a Protein Kinase inhibitor and a potential anticancer agent5

Description (简体中文)

包装
5, 25 g in glass bottle
Application
Reactant for:
• Synthesis of electron-deficient alkenes via stereoselective olefination of N-sulfonyl imines1
• Phosphine-catalyzed asymmetric addition reactions2
• Cysteine-catalyzed enantioselective intramolecular Rauhut-Currier reaction3
• Wittig olefination4
• Synthesis of aigialomycin D, a Protein Kinase inhibitor and a potential anticancer agent5